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具有快速自愈、增强防冰/除冰性能及出色稳定性的光热固体光滑表面

Photothermal Solid Slippery Surfaces with Rapid Self-Healing, Improved Anti/De-Icing and Excellent Stability.

作者信息

Tan Shengda, Han Xiao, Cheng Shuman, Guo Pu, Wang Xuan, Che Pengda, Jin Rongyu, Jiang Lei, Heng Liping

机构信息

Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education, Beijing Key Laboratory of Bio-inspired Energy Materials and Devices, School of Chemistry, Beihang University, Beijing, 100191, China.

出版信息

Macromol Rapid Commun. 2023 Mar;44(6):e2200816. doi: 10.1002/marc.202200816. Epub 2023 Feb 3.

Abstract

Icing phenomenon that occurs universally in nature and industry gets a great impact on human life. Over the past decades, extensive efforts have been made for a wide range of anti-icing/deicing surfaces, but the preparation of anti-icing/deicing interfaces that combine stability, rapid self-healing and excellent anti-icing/deicing performance remains a challenge. In this study, a photothermal solid slippery surface with excellent comprehensive performance is prepared by integrating cellulose acetate film, carbon nanotubes with paraffin wax (CCP). Apart from the excellent anti-icing and deicing properties at -17 ± 1.0 °C under 1 sun illumination, the surface can further achieve deicing at temperatures as low as -22 ± 1.0 °C under infrared light. The fabricated surface also exhibits great stability when placed in harsh conditions such as underwater or ultra-low temperature environments for over 30 days. Even when suffering from physical damage, the prepared surface can rapidly self-repair under 1 sun illumination or near-infrared (NIR) illumination within 16.0 ± 1.5 s. Due to the rapid and repeatable self-healing performance, the lubricating properties of the interface material do not deteriorate even after 50 repeated abrasing-repairing cycles. The photothermal solid slippery surface possesses wide-ranging applications and commercial value at high latitude and altitude regions.

摘要

结冰现象在自然界和工业中普遍存在,对人类生活产生了重大影响。在过去几十年里,人们为制备各种防冰/除冰表面付出了巨大努力,但制备兼具稳定性、快速自愈性和优异防冰/除冰性能的防冰/除冰界面仍然是一项挑战。在本研究中,通过将醋酸纤维素膜、碳纳米管与石蜡(CCP)相结合,制备了一种具有优异综合性能的光热固体光滑表面。除了在1个太阳光照下于-17 ± 1.0°C具有优异的防冰和除冰性能外,该表面在红外光下温度低至-22 ± 1.0°C时也能进一步实现除冰。当置于水下或超低温环境等恶劣条件下超过30天时,所制备的表面还表现出极大的稳定性。即使受到物理损伤,制备的表面在1个太阳光照或近红外(NIR)光照下也能在16.0 ± 1.5秒内迅速自愈。由于具有快速且可重复的自愈性能,即使经过50次反复磨损-修复循环,界面材料的润滑性能也不会恶化。这种光热固体光滑表面在高纬度和高海拔地区具有广泛的应用和商业价值。

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