Xiao Xin, Yao Fang, Huang Min, Wei Jue, Wang Jian
Key Laboratory of Materials and Surface Technology (Ministry of Education), School of Materials Science and Engineering, Xihua University, Chengdu 610039, People's Republic of China.
Langmuir. 2024 Aug 13;40(32):17151-17159. doi: 10.1021/acs.langmuir.4c02419. Epub 2024 Aug 1.
Solving the problem of ice accumulation on solid surfaces is of great significance to the economic development of the country and the safety of people's lives. In this work, a coating with multifunctional photothermal/electrothermal solid-state lubrication (PEL) for anti-icing/deicing was prepared in layers based on the intrinsic properties of silicone oil and paraffin wax in combination with conductive graphite and multiwalled carbon nanotubes. Silicone oils and paraffins are used as lubricating media giving the coating excellent lubricity, which results in a water sliding angle (SA) of only 12° on the PEL surface. Meanwhile, PEL shows favorable static and dynamic ice resistance at low temperatures; at -10 °C, the freezing time of water droplets on the PEL surface is extended by at least 4 times compared to the bare substrate. Furthermore, PEL also offers highly efficient photothermal and electrothermal deicing performance, which can effectively remove the accumulated ice at a light intensity of 0.6 kW/m or an EPD of 0.1 W/cm. Meanwhile, the synergistic deicing mechanism of photothermal and electrothermal was verified at -20 °C. Interestingly, the coating shows heat-assisted healing ability due to the phase change characteristic of paraffin wax, which allows the coating to regain lubricating properties after mechanical abrasion. Therefore, this work provides a reliable way for the design of stable all-weather anti-icing/deicing strategies at low temperatures.
解决固体表面的结冰问题对国家经济发展和人民生命安全具有重要意义。在这项工作中,基于硅油和石蜡的固有特性,结合导电石墨和多壁碳纳米管,分层制备了一种具有多功能光热/电热固态润滑(PEL)的防冰/除冰涂层。硅油和石蜡用作润滑介质,使涂层具有优异的润滑性,在PEL表面的水滑动角(SA)仅为12°。同时,PEL在低温下表现出良好的静态和动态抗冰性能;在-10°C时,与裸露基材相比,PEL表面水滴的冻结时间延长了至少4倍。此外,PEL还具有高效的光热和电热除冰性能,在光强为0.6kW/m或电场强度为0.1W/cm时,能有效去除积聚的冰。同时,在-20°C时验证了光热和电热的协同除冰机制。有趣的是,由于石蜡的相变特性,该涂层具有热辅助修复能力,使其在机械磨损后能够恢复润滑性能。因此,这项工作为设计低温下稳定的全天候防冰/除冰策略提供了一条可靠的途径。