钯（II）催化偶氮苯甲酰胺的选择性β-C-H官能化反应

Pd(II)-catalyzed selective β-C-H functionalization of azobenzene carboxamides.

作者信息

Padmavathi Rayavarapu, Babu Srinivasarao Arulananda

机构信息

Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Knowledge City, Sector 81, SAS Nagar, Mohali, Manauli P.O., Punjab, 140306, India.

出版信息

Org Biomol Chem. 2023 Mar 29;21(13):2689-2694. doi: 10.1039/d2ob02261c.

DOI:10.1039/d2ob02261c

PMID:36691730

Abstract

We report a Pd(II)-catalyzed bidentate directing group 8-aminoquinoline-aided, site-selective β-C-H functionalization protocol for assembling modified azobenzene carboxamides. Considering the importance of azobenzenes in chemical sciences, this paper reports a new route for enriching the library of modified azobenzene motifs.

摘要

我们报道了一种钯（II）催化的双齿导向基团8-氨基喹啉辅助的位点选择性β-C-H官能化方案，用于组装修饰的偶氮苯甲酰胺。鉴于偶氮苯在化学科学中的重要性，本文报道了一种丰富修饰偶氮苯基序库的新途径。