混合金属卤化物钙钛矿半导体中的电荷传输。

Charge transport in mixed metal halide perovskite semiconductors.

作者信息

Senanayak Satyaprasad P, Dey Krishanu, Shivanna Ravichandran, Li Weiwei, Ghosh Dibyajyoti, Zhang Youcheng, Roose Bart, Zelewski Szymon J, Andaji-Garmaroudi Zahra, Wood William, Tiwale Nikhil, MacManus-Driscoll Judith L, Friend Richard H, Stranks Samuel D, Sirringhaus Henning

机构信息

Nanoelectronics and Device Physics Lab, National Institute of Science Education and Research, School of Physical Sciences, HBNI, Jatni, India.

Optoelectronics Group, Department of Physics, Cavendish Laboratory, University of Cambridge, Cambridge, UK.

出版信息

Nat Mater. 2023 Feb;22(2):216-224. doi: 10.1038/s41563-022-01448-2. Epub 2023 Jan 26.

Abstract

Investigation of the inherent field-driven charge transport behaviour of three-dimensional lead halide perovskites has largely remained challenging, owing to undesirable ionic migration effects near room temperature and dipolar disorder instabilities prevalent specifically in methylammonium-and-lead-based high-performing three-dimensional perovskite compositions. Here, we address both these challenges and demonstrate that field-effect transistors based on methylammonium-free, mixed metal (Pb/Sn) perovskite compositions do not suffer from ion migration effects as notably as their pure-Pb counterparts and reliably exhibit hysteresis-free p-type transport with a mobility reaching 5.4 cm V s. The reduced ion migration is visualized through photoluminescence microscopy under bias and is manifested as an activated temperature dependence of the field-effect mobility with a low activation energy (~48 meV) consistent with the presence of the shallow defects present in these materials. An understanding of the long-range electronic charge transport in these inherently doped mixed metal halide perovskites will contribute immensely towards high-performance optoelectronic devices.

摘要

由于在室温附近存在不良的离子迁移效应,以及在基于甲基铵和铅的高性能三维钙钛矿组合物中普遍存在的偶极无序不稳定性,对三维铅卤化物钙钛矿固有场驱动电荷传输行为的研究在很大程度上仍然具有挑战性。在这里,我们解决了这两个挑战,并证明基于无甲基铵的混合金属(Pb/Sn)钙钛矿组合物的场效应晶体管不像其纯铅对应物那样明显受到离子迁移效应的影响,并且可靠地表现出无滞后的p型传输,迁移率达到5.4 cm V s。通过偏压下的光致发光显微镜观察到离子迁移的减少,这表现为场效应迁移率的激活温度依赖性,其低激活能(约48 meV)与这些材料中存在的浅缺陷一致。对这些固有掺杂的混合金属卤化物钙钛矿中远程电子电荷传输的理解将极大地有助于高性能光电器件的发展。

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