解析窄带隙铅锡钙钛矿材料及光伏器件的降解途径
Disentangling degradation pathways of narrow bandgap lead-tin perovskite material and photovoltaic devices.
作者信息
Rombach Florine M, Dasgupta Akash, Kober-Czerny Manuel, Jin Heon, Ball James M, Smith Joel A, Farrar Michael D, Snaith Henry J
机构信息
Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, Oxford, UK.
出版信息
Nat Commun. 2025 Jul 1;16(1):5450. doi: 10.1038/s41467-025-58489-9.
Narrow bandgap lead-tin perovskites are essential components of next-generation all-perovskite multi-junction solar cells. However, their poor stability under operating conditions hinders successful implementation. In this work, we systematically investigate the underlying mechanisms of this instability under combined heat and light stress (ISOS L-2 conditions) by measuring changes in phase, conductivity, recombination and current-voltage characteristics. We find an increased impact of the redistribution of mobile ions during device operation to be the primary driver of performance loss during stressing, with further losses caused by a slower increase in non-radiative recombination and background hole density. Crucially, the dominant degradation mode changes with different hole transport materials, which we attribute to variations in iodine vacancy generation rates. By quantifying the impact of these mechanisms on device performance, we provide critical insights for improving the operational stability of lead-tin perovskite solar cells.
窄带隙铅锡钙钛矿是下一代全钙钛矿多结太阳能电池的关键组件。然而,它们在工作条件下稳定性较差,这阻碍了其成功应用。在这项工作中,我们通过测量相、电导率、复合以及电流-电压特性的变化,系统地研究了在热和光联合应力(ISOS L-2条件)下这种不稳定性的潜在机制。我们发现,器件运行过程中移动离子重新分布的影响增加是应力作用下性能损失的主要驱动因素,非辐射复合和背景空穴密度的缓慢增加导致了进一步的损失。至关重要的是,主导降解模式随不同的空穴传输材料而变化,我们将其归因于碘空位产生速率的差异。通过量化这些机制对器件性能的影响,我们为提高铅锡钙钛矿太阳能电池的运行稳定性提供了关键见解。
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