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通过润湿和流动实验评估水合物浆液输送特性的综合方法。

Combined Approach to Evaluate Hydrate Slurry Transport Properties through Wetting and Flow Experiments.

作者信息

Fossen Martin, Hatscher Stephan, Ugueto Luis

机构信息

Multiphase Flow, Department of Process Technology, SINTEF AS, 0314Oslo, Norway.

Wintershall DEA Norge AS, Jåttåflaten 27, 4020Stavanger, Norway.

出版信息

ACS Omega. 2023 Jan 9;8(3):2992-3006. doi: 10.1021/acsomega.2c05773. eCollection 2023 Jan 24.

Abstract

A condensate oil system was evaluated with respect to its hydrate properties by two experimental methods, namely, the wetting index (WI) procedure and a flow loop called the wheel flow loop. The WI was used to initially indicate the efficiency of a gas hydrate antiagglomerant (AA), while the wheel flow loop was used for evaluating the transport properties of systems without and with AA. The results provide new insight into the effect of water cut and flow properties on the risk of hydrate plugging. The test case used in the study was a relevant field from the Vega gas condensate asset on the Norwegian continental shelf. This asset is currently producing using continuous monoethylene glycol (MEG) injection as a hydrate prevention philosophy. The wettability of the hydrate particles was determined for uninhibited, underinhibited (10% MEG), and AA-inhibited systems, and the results indicated favorable wettability of the AA-protected system by changing the emulsion inversion point to higher water cuts. Furthermore, the wettability data were then confirmed by flow tests utilizing SINTEF's wheel flow loop. Moreover, both uninhibited and underinhibited systems led to plugging upon hydrate formation, indicating the need for optimized AA concentrations for a given fluid system and water cut. The overall results show that the WI combined with the wheel flow loop or similar equipment is an effective method for better selection and description of the plugging potential and transport properties for gas hydrate systems.

摘要

通过两种实验方法,即润湿性指数(WI)程序和一种称为轮式流动回路的流动环路,对凝析油系统的水合物特性进行了评估。WI最初用于指示气体水合物抗聚剂(AA)的效率,而轮式流动环路则用于评估有无AA时系统的输送特性。研究结果为含水率和流动特性对水合物堵塞风险的影响提供了新的见解。该研究中使用的测试案例来自挪威大陆架上Vega凝析气资产的一个相关领域。该资产目前采用连续注入单乙二醇(MEG)作为水合物预防策略进行生产。测定了未加抑制剂、抑制剂不足(10%MEG)和AA抑制系统中水合物颗粒的润湿性,结果表明,通过将乳液转相点改变为更高的含水率,AA保护系统具有良好的润湿性。此外,然后利用SINTEF的轮式流动环路通过流动试验证实了润湿性数据。此外,未加抑制剂和抑制剂不足的系统在水合物形成时都会导致堵塞,这表明对于给定的流体系统和含水率,需要优化AA浓度。总体结果表明,WI与轮式流动环路或类似设备相结合是一种有效方法,可更好地选择和描述气体水合物系统的堵塞潜力和输送特性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/674d/9878669/edacba5427ee/ao2c05773_0003.jpg

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