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尾矿粉对煤矸石基采矿胶结充填材料的改性效果及机理研究

Study on the modification effect and mechanism of tailings powder on coal gangue-based mining cementitious filling material.

作者信息

Qiu Jisheng, Luan Xi, Cheng Kun, Guan Xiao, Yang Minmin, Xiao Zhijie

机构信息

School of Architecture and Civil Engineering, Xi'an University of Science and Technology, 710054 No. 58 Yanta Rd., Xi'an, Shaanxi, People's Republic of China.

出版信息

Environ Sci Pollut Res Int. 2023 Apr;30(16):46038-46057. doi: 10.1007/s11356-023-25459-x. Epub 2023 Jan 30.

Abstract

Based on the problems of high carbon emission and high cost of traditional mining methods and filling materials, the tailings powder modified Coal Gangue-based Cementitious Backfill Material (CGCBM) was used for paste filling mining. In this study, the samples were prepared with different tailings powder content and different curing ages. The compressive strength test, XRD, SEM test, and NMR test were used to explore the changes of macroscopic strength and microstructure of the material. The results show that adding 50% tailings powder has the most obvious optimization effect on the performance of CGCBM. Tailings powder particles fill the surface holes of the fine aggregate of coal gangue in the early cement hydration process, reduce the water absorption of the aggregate. In addition, the active substances such as CaSiO play the pozzolanic effect, stimulate the secondary hydration of slurry, make the microstructure closely, and thus improve the macroscopic mechanical strength.

摘要

针对传统采矿方法和充填材料存在的高碳排放和高成本问题,采用尾矿粉改性煤矸石基胶结充填材料(CGCBM)进行膏体充填采矿。本研究制备了不同尾矿粉含量和不同养护龄期的试样,通过抗压强度试验、XRD、SEM试验和NMR试验,探究材料宏观强度和微观结构的变化。结果表明,添加50%尾矿粉对CGCBM性能的优化效果最为明显。在水泥水化初期,尾矿粉颗粒填充煤矸石细骨料表面孔隙,降低了骨料吸水率。此外,CaSiO等活性物质发挥火山灰效应,激发浆体二次水化,使微观结构致密,从而提高宏观力学强度。

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