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膨润土对煤矸石/尾矿胶结充填料性能改善的初步研究:流动性能、力学性能及渗透性

A Preliminary Study on the Improvement of Gangue/Tailing Cemented Fill by Bentonite: Flow Properties, Mechanical Properties and Permeability.

作者信息

Wang Hongsheng, Chen Dengfeng, Guo Ruihong, Tian Jiahao, Li Bin

机构信息

School of Energy Engineering, Xi'an University of Science and Technology, Xi'an 710054, China.

Institute of Rock Burst Prevention and Control, Xi'an University of Science and Technology, Xi'an 710054, China.

出版信息

Materials (Basel). 2023 Oct 22;16(20):6802. doi: 10.3390/ma16206802.

Abstract

Backfill mining has significant advantages in safe mining, solid waste utilization and ecological environmental protection, but solid waste materials (tailings, gangue and coal gasification slag, etc.), as derivative residues of the chemical and metallurgical industries, contain a large number of heavy metal elements, which is posing great challenges to the underground environment after backfill. In order to study the feasibility of bentonite for reducing the permeability of gangue/tailing sand cemented backfill body, relevant tests were carried out from the basic performance index, flow performance and mechanical properties of paste backfill materials. The test results show that bentonite has a significant effect on the water secretion rate of cemented fillers, and also promotes the improvement of slump and diffusion diameter of backfill slurry. The enhancement effect of mechanical properties in the early stage is not obvious, mainly concentrated in the middle and late stages of specimen curing. With the increase of bentonite content, the 28-day uniaxial compressive strength increased from 7.1 MPa and 7.9 MPa to 8.7 MPa and 9.0 MPa, respectively. Bentonite is filled between the pores of the cemented backfill with its fine particles and water swelling, which can reduce the porosity and permeability of the gangue and tailings cemented backfill. Therefore, on the premise of satisfying the flow and mechanical properties of paste backfill, bentonite can be used to improve the permeability of cemented backfill and reduce the leaching and migration of heavy metal ions.

摘要

充填采矿法在安全开采、固体废弃物利用和生态环境保护方面具有显著优势,但固体废弃物材料(尾矿、煤矸石和煤气化炉渣等)作为化工和冶金行业的衍生废渣,含有大量重金属元素,这对充填后的地下环境构成了巨大挑战。为研究膨润土降低煤矸石/尾砂胶结充填体渗透系数的可行性,从膏体充填材料的基本性能指标、流动性能和力学性能等方面开展了相关试验。试验结果表明,膨润土对胶结充填料的泌水率有显著影响,同时也促进了充填浆液坍落度和扩散直径的提高。力学性能的增强作用在早期不明显,主要集中在试件养护的中后期。随着膨润土含量的增加,28天单轴抗压强度分别从7.1MPa和7.9MPa提高到8.7MPa和9.0MPa。膨润土以其细颗粒和遇水膨胀特性填充在胶结充填体的孔隙之间,可降低煤矸石和尾矿胶结充填体的孔隙率和渗透系数。因此,在满足膏体充填流动性能和力学性能的前提下,膨润土可用于改善胶结充填体的渗透性,减少重金属离子的溶出和迁移。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aaa6/10608461/14cd57f98ed2/materials-16-06802-g001.jpg

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