Chen Xiaobing, Kuroda Daniel G
Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, USA.
Chem Commun (Camb). 2023 Feb 9;59(13):1849-1852. doi: 10.1039/d2cc05645c.
The conduction mechanism of a family of high concentration lithium electrolytes (HCEs) is investigated. It is found in all HCEs that the molecular motions are regulated by the anion size and correlated to the HCE ionic resistivity. From the results, a mechanism involving highly correlated ionic networks is derived.
研究了一类高浓度锂电解质(HCEs)的传导机制。在所有HCEs中发现,分子运动受阴离子大小的调节,并与HCE离子电阻率相关。根据这些结果,推导了一种涉及高度相关离子网络的机制。