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高浓度锂离子电解质中的离子传导机制。

Ionic conduction mechanism in high concentration lithium ion electrolytes.

作者信息

Chen Xiaobing, Kuroda Daniel G

机构信息

Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, USA.

出版信息

Chem Commun (Camb). 2023 Feb 9;59(13):1849-1852. doi: 10.1039/d2cc05645c.

Abstract

The conduction mechanism of a family of high concentration lithium electrolytes (HCEs) is investigated. It is found in all HCEs that the molecular motions are regulated by the anion size and correlated to the HCE ionic resistivity. From the results, a mechanism involving highly correlated ionic networks is derived.

摘要

研究了一类高浓度锂电解质(HCEs)的传导机制。在所有HCEs中发现,分子运动受阴离子大小的调节,并与HCE离子电阻率相关。根据这些结果,推导了一种涉及高度相关离子网络的机制。

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