镁硼氢化物-乙二胺固态镁离子电解质体系的结构见解。
Structural insight into the magnesium borohydride - ethylenediamine solid-state Mg-ion electrolyte system.
机构信息
Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain (UCLouvain), 1348, Louvain-la-Neuve, Belgium.
Institute for Applied Materials-Energy Storage Systems (IAM-ESS), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein, Germany.
出版信息
Dalton Trans. 2023 Feb 21;52(8):2404-2411. doi: 10.1039/d2dt03567g.
A highly complex crystal structure of stoichiometric Mg()(BH) was solved from single crystal synchrotron X-ray diffraction and confirmed by neutron powder diffraction (NPD) on isotopically substituted Mg()(BD). We highlight the role of the amorphous Mg(BH) in the reactivity of the Mg(BH)- system and characterized a previously overlooked phase, Mg()(BH).
我们通过单晶同步辐射 X 射线衍射解析并通过对同位素取代的 Mg()(BD)的中子粉末衍射 (NPD)证实了化学计量比 Mg()(BH)的高度复杂晶体结构。我们强调了非晶态 Mg(BH)在 Mg(BH)-体系反应性中的作用，并对一个以前被忽视的相 Mg()(BH)进行了表征。
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