使用基于杯[4]芳烃的双膦配体合成三价铑（III）二氮配合物。
Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand.
机构信息
Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, CV4 7AL, UK.
Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstraße 2, Leipzig, D-04103, Germany.
出版信息
Chem Commun (Camb). 2023 Feb 16;59(15):2150-2152. doi: 10.1039/d2cc06837k.
Abstract
The synthesis and characterisation of the rhodium(III) dinitrogen complex [Rh(2,2'-biphenyl)(CxP)(N)] are described, where CxP is a -spanning calix[4]arene-based diphosphine and the dinitrogen ligand is projected into the cavity of the macrocycle.
摘要
描述了三价铑（III）二氮配合物[Rh(2,2'-联苯)(CxP)(N)]的合成和表征，其中 CxP 是一种 - 桥联杯[4]芳烃基双膦配体，二氮配体被投射到大环的空腔中。
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