Terminal end-on coordination of dinitrogen versus isoelectronic CO: A comparison using the charge displacement analysis.

The metal dinitrogen bonding in a wide series of terminal end-on dinitrogen complexes is investigated with the charge displacement analysis based on natural orbitals of chemical valence (CD-NOCV). The effect of the σ donation and π backdonation on the NN bond are discussed and compared with the observations for a series of carbonyl complexes, published in 2016 by Tarantelli et al. The σ donation is relative invariant over the series of dinitrogen complexes and has no significant effect on the NN bond strength, whereas the π backdonation causes a considerable elongation of the NN bond. Some uncommon examples of weakly bound dinitrogen with blue-shifted stretching frequency compared to free N (ν = 2330 cm ) are known. The dinitrogen bonding in these complexes is simulated with a point charge. Apparently, electrostatics account for the shortened N─N bond in these systems.