Biodegradable chitosan-graphene oxide as an affective green filler for improving of properties in epoxy nanocomposites.

In this work, we investigated the effect of biodegradable Chitosan-encapsulated Graphene Oxide (CGO) on the morphology and properties of epoxy composites prepared using solution mixing with different filler loadings. The microstructures and properties of chitosan-GO and composites were studied using FTIR, XRD, SEM, TEM, tensile, impact, bending analysis, DMTA and TG tests. Microstructural observations confirmed that the CGO composition and its content in the matrix affected the distribution of fillers in the epoxy matrix. Mechanical and thermal tests indicated that the loading level of CGO and the ratio of chitosan to GO were the main factors that changed the strength of epoxy/CGOs composites. The tensile analysis confirmed that nanocomposites containing CGO exhibited a 65 % increase in elastic modulus due to the improved load transfer as a result of interfacial interactions between CGO and the matrix. DMTA analysis showed that the presence of CGO in the epoxy matrix increased T of the composite by ~30 °C. In the TGA test, although the introduction of CGO caused higher decomposition temperature of the CGO filled resins. CGO enhanced the final properties of epoxy-based nanocomposites as a result of the synergistic effect of chitosan and GO and the formation of 3-D CGO structures in the epoxy matrix.