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用于生产溶解级浆粕和沼气的蕉麻纤维预水解苏打法制浆

Prehydrolysis soda pulping of Enset fiber for production of dissolving grade pulp and biogas.

作者信息

Lemma Hanna Berhanu, Freund Christian, Yimam Abubeker, Steffen Friedrich, Saake Bodo

机构信息

University of Hamburg Chemial Wood Technology Hamburg Germany

Addis Ababa Institute of Technology, Addis Ababa University, Chemical, and Bio Engineering Addis Ababa Ethiopia.

出版信息

RSC Adv. 2023 Feb 1;13(7):4314-4323. doi: 10.1039/d2ra07220c. eCollection 2023 Jan 31.

Abstract

Massive tonnes of fibrous residues are produced during the harvesting of the Enset plant for food preparation. The fibers are characterized by high cellulose and hemicellulose content and low lignin and extractive content. These make the fiber a good candidate for its concurrent valorization aimed at dissolving grade pulp and biogas. Prehydrolysis soda pulping was performed using steam pretreatment as a prehydrolysis step at a severity ranging from 2.95 to 4.13. The steamed fiber (PH fiber) was subjected to subsequent soda pulping under mild (160 °C and 16% alkali concentration) and severe (180 °C and 24% alkali concentration) pulping conditions. At higher steaming severity, a pulp with a xylose content of <4% and glucose content of 96% was obtained. A simple bleaching stage was envisaged to develop oxygen-peroxide (OQP), oxygen-double peroxide (OQPP, and OQPP) and oxygen-peroxide-chlorine dioxide (OQPD) sequences. Brightnesses up to ∼85% ISO could be reached for all sequences with CUEN viscosities of ∼350-500 ml g. Higher viscosities with higher brightness were achieved mainly by OQPD sequence. However, even with OQP and OQPP sequences the pulps met the requirements for lyocell production. An intense steam treatment reduces the biochemical methane potential (BMP) of prehydrolysis liquid (PHL) from 462 ml g to 315 ml g The reduction might be due to the inhibition effect of furan concentration increase in the corresponding PHL from 2 ppm to 24 ppm. However, due to the higher yield and carbohydrate concentration of the prehydrolysis liquid, the biogas production volumes per initial raw material were still higher at higher steaming severity.

摘要

在为制备食物而收割埃塞俄比亚香蕉植株的过程中会产生大量的纤维残渣。这些纤维的特点是纤维素和半纤维素含量高,木质素和提取物含量低。这些特性使这种纤维成为同时实现其增值利用(旨在生产溶解级纸浆和沼气)的良好候选材料。采用蒸汽预处理作为预水解步骤进行预水解苏打法制浆,其蒸煮强度范围为2.95至4.13。对蒸煮后的纤维(预水解纤维)在温和(160℃和16%碱浓度)和剧烈(180℃和24%碱浓度)的制浆条件下进行后续苏打法制浆。在较高的蒸煮强度下,可获得木糖含量<4%且葡萄糖含量为96%的纸浆。设想了一个简单的漂白阶段来开发氧-过氧化氢(OQP)、氧-双过氧化氢(OQPP和OQPP)以及氧-过氧化氢-二氧化氯(OQPD)序列。所有序列的亮度均可达到约85%ISO,铜乙二胺粘度约为350 - 500 ml/g。主要通过OQPD序列实现了更高的粘度和更高的亮度。然而,即使采用OQP和OQPP序列,这些纸浆也满足了莱赛尔纤维生产的要求。强烈的蒸汽处理使预水解液(PHL)的生化甲烷潜力(BMP)从462 ml/g降至3'15 ml/g。这种降低可能是由于相应的预水解液中呋喃浓度从2 ppm增加到24 ppm的抑制作用。然而,由于预水解液的产率和碳水化合物浓度较高,在较高的蒸煮强度下,每单位初始原料的沼气产量仍然更高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac53/9890577/70f3498f32c7/d2ra07220c-f1.jpg

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