增强 Au 团簇在 CO 光还原中的耐久性 在基于 Cu 的金属有机骨架中的封装。
Enhancing the durability of Au clusters in CO photoreduction encapsulation in Cu-based metal-organic frameworks.
机构信息
Anhui Engineering Research Center of Carbon Neutrality, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241002, Anhui, P. R. China.
School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246011, Anhui, P. R. China.
出版信息
Chem Commun (Camb). 2023 Feb 21;59(16):2299-2302. doi: 10.1039/d2cc06719f.
Here, we report the encapsulation of Au nanoclusters in a Cu(BTC) metal-organic framework (Au@Cu-BTC), which can achieve CO photoreduction for selective CO production in a gas-solid reaction system at low-concentration CO atmospheres (even to 0.1%), with remarkably enhanced durability up to at least 48 h.
在这里，我们报告了将金纳米团簇封装在铜（BTC）金属有机骨架中（Au@Cu-BTC），它可以在低浓度 CO 气氛（甚至低至 0.1%）的气固反应体系中实现 CO 的光还原，用于选择性 CO 生产，具有显著增强的耐久性，至少可达 48 小时。
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