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种子介导的多壳层纳米铁氧体在第一和第二光学生物窗口内近红外光刺激引起的温度效应。

Temperature effects induced by NIR photo-stimulation within I and II optical biological windows of seed-mediated multi-shell nanoferrites.

作者信息

Kulpa-Greszta Magdalena, Tomaszewska Anna, Dziedzic Andrzej, Pązik Robert

机构信息

Department of Biotechnology, Institute of Biology and Biotechnology, College of Natural Sciences, University of Rzeszow, Pigonia 1, 35-310 Rzeszow, Poland.

Department of Spectroscopy and Materials, Institute of Physics, College of Natural Sciences, University of Rzeszow, Pigonia 1, 35-310 Rzeszow, Poland.

出版信息

Dalton Trans. 2023 Feb 28;52(9):2580-2591. doi: 10.1039/d2dt04178b.

Abstract

Different types of ferrite core-shell structures, namely CoFeO@CoFeO, CoFeO@FeO, CoFeO@MnFeO, and CoFeO@MnFeO@ZnFeO, were prepared by the seed-mediated approach. We show that this synthetic methodology offers great and important flexibility in the engineering of multi-shell ferrite nanoparticles which can be further used in various advanced applications. This impressive tool can be used for particle size tuning of homo- and heterostructures through convenient control of the concentration of metal acetylacetonates without the necessity of changing synthetic parameters, , temperature, time, and solvent. The contactless conversion of laser light within I (808 nm) and II (1122 nm) biological optical windows was studied on the fabricated ferrite core-shell materials which showed promising heating effects that can be a basis of their practical exploitation in the biomedical field.

摘要

通过种子介导法制备了不同类型的铁氧体核壳结构,即CoFeO@CoFeO、CoFeO@FeO、CoFeO@MnFeO和CoFeO@MnFeO@ZnFeO。我们表明,这种合成方法在多壳层铁氧体纳米颗粒的工程设计中提供了极大且重要的灵活性,这些纳米颗粒可进一步用于各种先进应用。这个令人印象深刻的工具可通过方便地控制金属乙酰丙酮化物的浓度来调节同质和异质结构的粒径,而无需改变合成参数,如温度、时间和溶剂。在制备的铁氧体核壳材料上研究了808纳米的近红外一区(I)和1122纳米的近红外二区(II)生物光学窗口内激光的非接触式转换,结果显示出有前景的热效应,这可作为其在生物医学领域实际应用的基础。

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