Achieving Functionality and Multifunctionality through Bulk and Interfacial Structuring of Colloidal-Crystal-Templated Materials.

Over the past 25 years, the field of colloidal crystal templating of inverse opal or three-dimensionally ordered macroporous (3DOM) structures has made tremendous progress. The degree of structural control over multiple length scales, understanding of mechanical properties, and complexity of systems in which 3DOM materials are a component have increased substantially. In addition, we are now seeing applications of 3DOM materials that make use of multiple features of their architecture at the same time. This Feature Article focuses on the different properties of 3DOM materials that provide functionality, including a relatively large surface area, the interconnectedness of the pores and the resulting good accessibility of the internal surface, the nanostructured features of the walls, the structural hierarchy and periodicity, well-defined surface roughness, and relative mechanical robustness at low density. It provides representative examples that illustrate the properties of interest related to applications including energy storage and conversion systems, sensors, catalysts, sorbents, photonics, actuators, and biomedical materials or devices.