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金属氧化物负载助催化剂对无模板ZnFeO纳米立方体光催化降解有机污染物和灭活细菌的协同作用

Synergistic role of metal oxide loading cocatalysts on photocatalytic degradation of organic pollutants and inactive bacteria over template-free ZnFeO nanocubes.

作者信息

Al-Ansari Mysoon M, Al-Humaid Latifah, Aldawsari Majdoleen, Al-Dahmash Nora Dahmash, Selvankumar T, Mythili R

机构信息

Department of Botany and Microbiology, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia.

Department of Botany and Microbiology, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia.

出版信息

Environ Res. 2023 Apr 15;223:115459. doi: 10.1016/j.envres.2023.115459. Epub 2023 Feb 9.

Abstract

For wastewater treatment, a highly reliable and ecologically friendly oxidation method is always preferred. This work described the production of a new extremely effective visible light-driven AgO loaded ZnFeO nanocomposties photocatalyst using a wet impregnation technique. Under visible light irradiation, the produced AgO loaded ZnFeO nanocomposties were used in the photodegradation of rhodamine B (RhB) and Reactive Red 120 (RR120) dyes. Analysis using X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy revealed that AgO nanoparticles were well dispersed on the surface of ZnFeO NPs and that the AgO loaded ZnFeO NPs were created. When compared with bare ZnFeO NPs, AgO-loaded ZnFeO nanocomposites showed better photocatalytic activity for RhB and RR120 degradation under visible light (>420 nm) illumination. The reaction kinetics and degradation methodology, in addition to the photocatalytic degradation functions of AgO-loaded ZnFeO nanocomposites, were thoroughly investigated. The 3 wt% AgO loaded ZnFeO nanocomposites have a 99% removal efficiency for RhB and RR120, which is about 2.4 times greater than the ZnFeO NPs and simple combination of 1 wt% and 2 wt% AgO loaded ZnFeO nanocomposites. Furthermore, the 3 wt% AgO loaded ZnFeO nanocomposites demonstrated consistent performance without decreasing activity throughout 3 consecutive cycles, indicating a potential approach for the photo-oxidative destruction of organic pollutants as well as outstanding antibacterial capabilities. According to the findings of the experiments, produced new nanoparticles are an environmentally friendly, cost-efficient option for removing dyes, and they were successful in suppressing the development of Gram-negative and Gram-positive bacteria.

摘要

对于废水处理而言,人们总是更青睐高度可靠且生态友好的氧化方法。这项工作描述了一种新型高效可见光驱动的负载AgO的ZnFeO纳米复合光催化剂的制备,该催化剂采用湿浸渍技术合成。在可见光照射下,所制备的负载AgO的ZnFeO纳米复合材料用于罗丹明B(RhB)和活性红120(RR120)染料的光降解。通过X射线衍射、傅里叶变换红外光谱、X射线光电子能谱和透射电子显微镜分析表明,AgO纳米颗粒均匀分散在ZnFeO纳米颗粒表面,从而形成了负载AgO的ZnFeO纳米颗粒。与裸露的ZnFeO纳米颗粒相比,负载AgO的ZnFeO纳米复合材料在可见光(>420 nm)照射下对RhB和RR120的降解表现出更好的光催化活性。此外,还深入研究了负载AgO的ZnFeO纳米复合材料的反应动力学、降解方法及其光催化降解功能。3 wt%负载AgO的ZnFeO纳米复合材料对RhB和RRl20的去除效率达到99%,约为ZnFeO纳米颗粒以及1 wt%和2 wt%负载AgO的ZnFeO纳米复合材料简单组合去除效率的2.4倍。此外,3 wt%负载AgO 的ZnFeO纳米复合材料在连续3个循环中表现出稳定的性能且活性未降低,这表明该材料在光氧化破坏有机污染物方面具有潜在应用价值,同时还具有出色的抗菌能力。根据实验结果,所制备的新型纳米颗粒是一种环境友好、成本效益高的染料去除材料,并且成功抑制了革兰氏阴性菌和革兰氏阳性菌的生长。

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