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提高金属离子掺杂 FeO 纳米粒子的效率:用于从水介质中去除有机染料的光催化剂。

Improving the efficiency of metal ions doped FeO nanoparticles: Photocatalyst for removal of organic dye from aqueous media.

机构信息

Department of Environmental Engineering and Management, Chaoyang University of Technology, Taichung, 41349, Taiwan.

Department of Physics and Astronomy, College of Science, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi Arabia.

出版信息

Chemosphere. 2023 Oct;337:139229. doi: 10.1016/j.chemosphere.2023.139229. Epub 2023 Jun 22.

Abstract

The metal ion-based nanocomposite photocatalysts were accepted to exhibit a wide range of photocatalytic and biological applications. In this paper, we synthesize bare FeO, 1 wt% metal (Ag, Co, and Cu) doped FeO nanoparticles (NPs) using a simple hydrothermal process and wet impregnation method. The as-prepared nanomaterials crystalline structure, shape, optical characteristics, and elemental composition were determined by using X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Scanning electron microscope (SEM), Energy-dispersive X-ray (EDS) and Transmission electron microscopy (TEM) techniques. Furthermore, the synthesized nanocomposites were utilized as a photosensitizer for the degradation of reactive red (RR120) and orange II (O-II) dyes under sunlight irradiation. The synthesized 1 wt% Ag-FeO (AgF) NPs samples exhibit a more exceptional catalytic performance of RR120 and O-II dyes (98.32%) within 120 min than the existing FeO, 1 wt% Co-FeO, and Cu-FeO NPs. The effect of parameters such as exciton formation under solar irradiation, charge recombination rate, and surface charge availability. The metal oxide-doped nanocomposite economic relevance is revealed by their long-term durability and recyclability in photodegradation reactions. The photocatalytic investigations show that the active species O, HO and h play an important role in the dye degradation process. This research might pave the opportunity for the sustainable development of greater photocatalysts for photodegradation and a wide range of environmental applications.

摘要

基于金属离子的纳米复合材料光催化剂被认为具有广泛的光催化和生物应用。在本文中,我们使用简单的水热法和湿浸渍法合成了纯 FeO 和 1wt%金属(Ag、Co 和 Cu)掺杂的 FeO 纳米颗粒(NPs)。所制备的纳米材料的晶体结构、形状、光学特性和元素组成通过 X 射线粉末衍射(XRD)、X 射线光电子能谱(XPS)、扫描电子显微镜(SEM)、能谱(EDS)和透射电子显微镜(TEM)技术确定。此外,所合成的纳米复合材料被用作光催化剂,用于在阳光照射下降解活性红(RR120)和橙色 II(O-II)染料。与现有的 FeO、1wt%Co-FeO 和 Cu-FeO NPs 相比,合成的 1wt%Ag-FeO(AgF)NPs 样品在 120min 内对 RR120 和 O-II 染料的催化性能更为优异(98.32%)。在阳光照射下形成激子、电荷复合率和表面电荷可用性等参数的影响。金属氧化物掺杂纳米复合材料的经济相关性通过其在光降解反应中的长期稳定性和可回收性得到了揭示。光催化研究表明,活性物种 O、HO 和 h 在染料降解过程中起着重要作用。这项研究为可持续发展更高效的光催化剂用于光降解和广泛的环境应用提供了机会。

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