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高固形物低木质素竹浆黑液的流变性和体积等温膨胀系数。

Rheological properties and volumetric isothermal expansivity of bamboo kraft black liquor with high solids content and low lignin content.

机构信息

College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an, 710021, China.

National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science and Technology, Xi'an, 710021, China.

出版信息

Sci Rep. 2023 Feb 10;13(1):2400. doi: 10.1038/s41598-023-29350-0.

Abstract

In this study, a certain percentage of lignin in original bamboo kraft black liquor (BKBL) was separated, and the residual BKBL with low lignin content was expected to be fed into the alkali recovery boiler to reduce the heat transfer load of the alkali recovery boiler. With the decrease in lignin content, the rheological properties/volumetric isothermal expansivity (VIE) of BKBL change. When the lignin content was 70% remaining in the original BKBL, the viscosity of BKBL with low lignin content is close to that of the passivated BKBL at the same solids content, the dynamic viscoelasticity is superior, and the VIE decreases by 57.2%. When the amount of desilication agent is 1.5%, the viscosity of BKBL with low lignin content did not change much, and the VIE increased sharply and was 62.7% higher than that of the passivated BKBL. Therefore, the combination of partial lignin separation process and sodium aluminate desilication process can effectively improve the ability of alkali recovery boiler to deal with BKBL and reduce the influence of "silicon interference".

摘要

在这项研究中,从原始竹浆黑液(BKBL)中分离出一定比例的木质素,预期将低木质素含量的剩余 BKBL 送入碱回收锅炉,以降低碱回收锅炉的传热负荷。随着木质素含量的降低,BKBL 的流变性/体积等温膨胀系数(VIE)发生变化。当原始 BKBL 中木质素含量剩余 70%时,低木质素含量 BKBL 的粘度接近具有相同固含量的钝化 BKBL,其动态粘弹性更优,VIE 降低了 57.2%。当脱硅剂用量为 1.5%时,低木质素含量 BKBL 的粘度变化不大,VIE 急剧增加,比钝化 BKBL 高 62.7%。因此,部分木质素分离工艺和偏铝酸钠脱硅工艺的结合可以有效提高碱回收锅炉处理 BKBL 的能力,降低“硅干扰”的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8a19/9918492/7770b0a6ad06/41598_2023_29350_Fig1_HTML.jpg

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