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厦门市农业土壤中有机氯农药的分布特征及影响因素。

Distribution Characteristics and Influencing Factors of Organochlorine Pesticides in Agricultural Soil from Xiamen City.

机构信息

School of Environmental Science and Technology, Xiamen University of Technology, Xiamen 361024, China.

Key Laboratory of Environmental Biotechnology (XMUT), Fujian Province University, Xiamen 361024, China.

出版信息

Int J Environ Res Public Health. 2023 Jan 20;20(3):1916. doi: 10.3390/ijerph20031916.

Abstract

The concentration and distribution of 15 organochlorine pesticides in the soil of Xiamen City were determined. Overall, among the 15 selected target pesticides, 14 organochlorine pesticides (OCPs) were detected (hexachlorobenzene was not). The range of detected pesticides was undetected-10.04 ng/g, the total detection rate was 35.2%, and the three pollutants with the highest detection rate in all samples were Heptachlor (66.7%), δ-Hexachlorocyclohexane (60.0%), and p, p'-Dichlorodiphenyldichloroethane (58.3%). The degree of pollution in descending order was Tong'an > Xiang'an > Jimei > Haicang. Linear regression analysis of soil properties and OCP concentration distribution revealed that OCPs were positively correlated with water content, dissolved organic carbon, and pH and negatively correlated with cation exchange capacity. The origin of OCPs was evaluated using the relationship between the parent compound and its metabolites, with possible new hexachlorocyclohexane and isomer (HCHs) input. By comparing the risk screening values of ΣHCHs and ΣDDTs in "Soil Environmental Quality Standards", the concentrations in all soil samples were lower than the standard values, which indicated that the OCP residues in Xiamen were very low.

摘要

测定了厦门市土壤中 15 种有机氯农药的浓度和分布。总体而言,在所选择的 15 种目标农药中,检测到 14 种有机氯农药(OCPs)(未检出六氯苯)。检出农药的范围为未检出-10.04ng/g,总检出率为 35.2%,在所有样品中检出率最高的三种污染物分别为七氯(66.7%)、δ-六氯环己烷(60.0%)和 p,p'-二氯二苯二氯乙烷(58.3%)。污染程度依次为同安>翔安>集美>海沧。土壤性质与 OCP 浓度分布的线性回归分析表明,OCPs 与含水量、溶解有机碳和 pH 值呈正相关,与阳离子交换容量呈负相关。利用母体化合物与其代谢物之间的关系评估了 OCPs 的来源,可能有新的六氯环己烷和异构体(HCHs)输入。通过比较“土壤环境质量标准”中ΣHCHs 和 ΣDDTs 的风险筛选值,所有土壤样品中的浓度均低于标准值,表明厦门的 OCP 残留非常低。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bcf/9915912/3ad70a33af73/ijerph-20-01916-g001.jpg

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