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将生物质作为修复重金属污染水的潜在材料的利用。

Valorization of Biomass as Potential Material for the Remediation of Heavy-Metals-Contaminated Waters.

机构信息

Multidisciplinary Postgraduate Program in Environmental Sciences, University Zone, Av. Manuel Nava 201, 2nd. Floor, San Luis Potosí 78000, Mexico.

Department of Inorganic Chemistry, Faculty of Science, University of Granada, 18071 Granada, Spain.

出版信息

Int J Environ Res Public Health. 2023 Jan 31;20(3):2559. doi: 10.3390/ijerph20032559.

Abstract

algae has become a major environmental issue due to its abundance in the Pacific Ocean with hundreds of tons reaching the beaches of the Mexican Caribbean every year. This generates large quantities of decomposing organic matter that have a negative impact on the region's economy and ecosystems. valorization has turned out to be a fundamental aspect to mitigate its environmental impact. This study proposes the use and application of untreated biomass for the decontamination of waters polluted with lead (Pb) and cadmium (Cd) through single and binary adsorption tests. Physicochemical and textural properties examined by SEM, XRD, and FT-IR elucidated that biomass is viable to be used as a potential environmental benign adsorbent, exhibiting Cd(II) and Pb(II) adsorption capacities as high as 240 mg g and 350 mg g, respectively, outperforming conventionally used adsorbents. This is attributed to its morphology, favorable surface charge distribution, and the presence of -OH and -COH groups. A strong affinity between the biomass and metal pollutants was evidenced by a thermodynamics study, showing a spontaneous and endothermic process. This work sets a practical route for the utilization of the biomass, demonstrating its applicability as a potential material for heavy-metal-polluted water remediation, making a substantial contribution to a circular economy system.

摘要

由于藻类在太平洋中大量繁殖,每年有数百吨藻类到达墨西哥加勒比海滩,藻类已成为一个主要的环境问题。这会产生大量的分解有机物,对该地区的经济和生态系统产生负面影响。为了减轻其对环境的影响,藻类的增值已成为一个重要的方面。本研究提出了使用未经处理的生物质进行单因子和双因子吸附实验,以去除受铅(Pb)和镉(Cd)污染的水。通过 SEM、XRD 和 FT-IR 对其物理化学和结构特性进行了检测,结果表明生物质是一种可行的潜在环境友好型吸附剂,对 Cd(II)和 Pb(II)的吸附容量分别高达 240 mg/g 和 350 mg/g,优于传统吸附剂。这归因于其形态、有利的表面电荷分布以及-OH 和-COH 基团的存在。热力学研究表明生物质和金属污染物之间存在很强的亲和力,这是一个自发和吸热的过程。这项工作为利用生物质提供了一条实用的途径,证明了其作为一种潜在的用于重金属污染水修复的材料的适用性,为循环经济系统做出了实质性贡献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5f20/9915137/877a321e67ea/ijerph-20-02559-g001.jpg

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