Biermaier Christian, Petz Phillip, Bechtold Thomas, Pham Tung
Research Institute of Textile Chemistry and Textile Physics, Universität Innsbruck, Hoechsterstrasse 73, 6850 Dornbirn, Austria.
Embedded Systems Laboratory, University of Applied Sciences Upper Austria, 4232 Hagenberg, Austria.
Materials (Basel). 2023 Jan 18;16(3):912. doi: 10.3390/ma16030912.
Conductive textiles play an important role in recent electronics development; however, one of the major challenges remains their machine-washing durability. For the investigation of the basic wash ageing mechanisms, we used copper-plated polyamide 66 and cellulose fabrics and developed a wet and dry operable flex tester with online resistance recording. The evaluation was supported by abrasion tests, cyclic elongation tests and tribological investigation of dry and wet textile-textile friction. It was found that the contribution of mechanical and chemical ageing to wash ageing strongly depends on the substrate material. A bad adhesion of copper on polyamide 66 leads to early fatigue while better stability of the copper on cellulose leads to a stronger resistance against ageing. For both substrates, the delamination of the copper layer was the root cause of the fatigue, which is facilitated by the washing solution. Finally, a cumulative fatigue model was developed and the determination of the end of lifetime by the intended use is discussed.
导电纺织品在近期的电子发展中发挥着重要作用;然而,其主要挑战之一仍然是机洗耐久性。为了研究基本的洗涤老化机制,我们使用了镀铜聚酰胺66和纤维素织物,并开发了一种可干湿操作的挠曲测试仪,可在线记录电阻。通过磨损试验、循环伸长试验以及干湿织物间摩擦的摩擦学研究对评估提供了支持。结果发现,机械老化和化学老化对洗涤老化的贡献很大程度上取决于基材。铜在聚酰胺66上的附着力差会导致早期疲劳,而铜在纤维素上的稳定性更好则会使其具有更强的抗老化能力。对于这两种基材,铜层的分层都是疲劳的根本原因,洗涤液会加剧这种情况。最后,建立了一个累积疲劳模型,并讨论了根据预期用途确定使用寿命终点的问题。