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少层石墨烯对通过数字光处理(DLP)3D打印生产的聚合物复合材料的硬度、强度和热物理性能复合体的影响。

The Effect of Few-Layer Graphene on the Complex of Hardness, Strength, and Thermo Physical Properties of Polymer Composite Materials Produced by Digital Light Processing (DLP) 3D Printing.

作者信息

Kidalov Sergey, Voznyakovskii Alexander, Vozniakovskii Aleksei, Titova Sofia, Auchynnikau Yvgenii

机构信息

Ioffe Institute, 194021 St. Petersburg, Russia.

Institute of Synthetic Rubber, 198035 St. Petersburg, Russia.

出版信息

Materials (Basel). 2023 Jan 29;16(3):1157. doi: 10.3390/ma16031157.

Abstract

The results of studying the effect of particles of few-layer graphene (FLG) synthesized by self-propagating high-temperature synthesis (SHS) on the complex of strength and thermo physical properties of polymer composite products obtained by digital light processing (DLP) 3D printing are presented. It was discovered to achieve an increase in thermophysical and strength parameters of polymers modified by FLG compared with samples made on the unmodified base resin. This result was achieved due to low defectiveness, namely the absence of Stone-Wales defects in the structure of FLG due to the homogeneous distribution of FLG over the volume of the polymer in the form of highly dispersed aggregates. It was possible to increase hardness by 120%, bending strength by 102%, Charpy impact strength by 205%, and thermal conductivity at 25 °C by 572% at concentrations of few-layer graphene of no more than 2 wt. %.

摘要

本文展示了对通过自蔓延高温合成(SHS)制备的少层石墨烯(FLG)颗粒,在数字光处理(DLP)3D打印所得聚合物复合产品的强度和热物理性能复合体方面影响的研究结果。研究发现,与未改性基础树脂制成的样品相比,用FLG改性的聚合物的热物理和强度参数有所提高。这一结果的实现得益于低缺陷率,即由于FLG以高度分散聚集体的形式均匀分布在聚合物体积中,FLG结构中不存在斯通-威尔士缺陷。在少层石墨烯浓度不超过2 wt.%的情况下,硬度可提高120%,弯曲强度提高102%,夏比冲击强度提高205%,25℃时的热导率提高572%。

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