• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

双光束热透镜光谱法测量热物理参数的准确性

Accuracy of Measurements of Thermophysical Parameters by Dual-Beam Thermal-Lens Spectrometry.

作者信息

Khabibullin Vladislav R, Franko Mladen, Proskurnin Mikhail A

机构信息

Analytical Chemistry Division, Chemistry Department, M.V. Lomonosov Moscow State University, d. 1, str. 3, Lenin Hills, GSP-1 V-234, Moscow 119991, Russia.

Laboratory for Environmental and Life Sciences, University of Nova Gorica, Vipavska 13, Rožna Dolina, 5000 Nova Gorica, Slovenia.

出版信息

Nanomaterials (Basel). 2023 Jan 20;13(3):430. doi: 10.3390/nano13030430.

DOI:10.3390/nano13030430
PMID:36770391
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9920435/
Abstract

Thermal-lens spectrometry is a sensitive technique for determination of physicochemical properties and thermophysical parameters of various materials including heterogeneous systems and nanoparticles. In this paper, we consider the issues of the correctness (trueness) of measurements of the characteristic time of the thermal-lens effect and, thus, of the thermal diffusivity determined by dual-beam mode-mismatching thermal lensing. As sources of systematic errors, major factors-radiation sources, sample-cell and detector parameters, and general measurement parameters-are considered using several configurations of the thermal-lens setups, and their contributions are quantified or estimated. Furthermore, with aqueous ferroin and Sudan I in ethanol as inert colorants, the effects of the intermolecular distance of the absorbing substance on the correctness of finding the thermophysical parameters are considered. The recommendations for checking the operation of the thermal-lens setup to ensure the maximum accuracy are given. The results obtained help reducing the impact of each investigated factor on the value of systematic error and correctly measure the thermophysical parameters using thermal-lens spectrometry.

摘要

热透镜光谱法是一种用于测定包括非均相体系和纳米颗粒在内的各种材料的物理化学性质和热物理参数的灵敏技术。在本文中，我们考虑了热透镜效应特征时间测量的正确性（准确性）问题，进而考虑了由双光束模式失配热透镜法测定的热扩散率的正确性问题。作为系统误差源，我们使用热透镜装置的几种配置，考虑了主要因素——辐射源、样品池和探测器参数以及一般测量参数，并对它们的贡献进行了量化或估计。此外，以亚铁菲绕啉水溶液和乙醇中的苏丹I作为惰性着色剂，考虑了吸收物质分子间距离对热物理参数测定正确性的影响。给出了检查热透镜装置运行以确保最大精度的建议。所获得的结果有助于减少每个研究因素对系统误差值的影响，并使用热透镜光谱法正确测量热物理参数。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/f3d87909d620/nanomaterials-13-00430-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/8e5eb2b3dead/nanomaterials-13-00430-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/7f2b41014d37/nanomaterials-13-00430-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/c988fdef5e43/nanomaterials-13-00430-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/083eff92a44e/nanomaterials-13-00430-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/35d42d2f7beb/nanomaterials-13-00430-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/4d459a14cebf/nanomaterials-13-00430-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/18ce82d8b291/nanomaterials-13-00430-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/1255339d0fa6/nanomaterials-13-00430-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/0a9c41c4976b/nanomaterials-13-00430-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/c4a7fc591923/nanomaterials-13-00430-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/721d66e1a55f/nanomaterials-13-00430-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/8837578c2d26/nanomaterials-13-00430-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/c62ae06cef15/nanomaterials-13-00430-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/a613767bdb58/nanomaterials-13-00430-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/6e3609d969da/nanomaterials-13-00430-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/e23e1baf9f3c/nanomaterials-13-00430-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/f0d719a0581d/nanomaterials-13-00430-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/9c24a6e00e0c/nanomaterials-13-00430-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/a32a6e33178f/nanomaterials-13-00430-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/c97a17fa17a0/nanomaterials-13-00430-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/9594a0021bf6/nanomaterials-13-00430-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/d1f849c328db/nanomaterials-13-00430-g022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/f3d87909d620/nanomaterials-13-00430-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/8e5eb2b3dead/nanomaterials-13-00430-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/7f2b41014d37/nanomaterials-13-00430-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/c988fdef5e43/nanomaterials-13-00430-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/083eff92a44e/nanomaterials-13-00430-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/35d42d2f7beb/nanomaterials-13-00430-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/4d459a14cebf/nanomaterials-13-00430-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/18ce82d8b291/nanomaterials-13-00430-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/1255339d0fa6/nanomaterials-13-00430-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/0a9c41c4976b/nanomaterials-13-00430-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/c4a7fc591923/nanomaterials-13-00430-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/721d66e1a55f/nanomaterials-13-00430-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/8837578c2d26/nanomaterials-13-00430-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/c62ae06cef15/nanomaterials-13-00430-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/a613767bdb58/nanomaterials-13-00430-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/6e3609d969da/nanomaterials-13-00430-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/e23e1baf9f3c/nanomaterials-13-00430-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/f0d719a0581d/nanomaterials-13-00430-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/9c24a6e00e0c/nanomaterials-13-00430-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/a32a6e33178f/nanomaterials-13-00430-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/c97a17fa17a0/nanomaterials-13-00430-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/9594a0021bf6/nanomaterials-13-00430-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/d1f849c328db/nanomaterials-13-00430-g022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4920/9920435/f3d87909d620/nanomaterials-13-00430-g023.jpg

相似文献

1
Accuracy of Measurements of Thermophysical Parameters by Dual-Beam Thermal-Lens Spectrometry.双光束热透镜光谱法测量热物理参数的准确性
Nanomaterials (Basel). 2023 Jan 20;13(3):430. doi: 10.3390/nano13030430.
2
The Thermophysical and Physicochemical Properties of the Aqueous Dispersion of Graphene Oxide Dual-Beam Thermal Lens Spectrometry.氧化石墨烯双光束热透镜光谱法水基分散体的热物理和物理化学性质
Nanomaterials (Basel). 2023 Jul 21;13(14):2126. doi: 10.3390/nano13142126.
3
Thermal Diffusivity of Aqueous Dispersions of Silicon Oxide Nanoparticles by Dual-Beam Thermal Lens Spectrometry.用双光束热透镜光谱法测定氧化硅纳米颗粒水分散体的热扩散率
Nanomaterials (Basel). 2023 Mar 10;13(6):1006. doi: 10.3390/nano13061006.
4
Features of High-Precision Photothermal Analysis of Liquid Systems by Dual-Beam Thermal Lens Spectrometry.双光束热透镜光谱法对液体系统进行高精度光热分析的特点。
Nanomaterials (Basel). 2024 Oct 1;14(19):1586. doi: 10.3390/nano14191586.
5
Mode-mismatched dual-beam differential thermal lensing with optical scheme design optimized using expert estimation for analytical measurements.通过使用专家估计进行优化的光学方案设计实现模式失配双光束差分热透镜，用于分析测量。
Appl Spectrosc. 2008 Apr;62(4):439-49. doi: 10.1366/000370208784046867.
6
Spectral and Lensing Characteristics of Gel-Derived Strontium Tartrate Single Crystals Using Dual-Beam Thermal Lens Technique.使用双光束热透镜技术研究凝胶法制备的酒石酸锶单晶的光谱和透镜特性
J Fluoresc. 2016 Sep;26(5):1549-54. doi: 10.1007/s10895-016-1875-3. Epub 2016 Jul 27.
7
Optimization of instrumental parameters of a near-field thermal-lens detector for capillary electrophoresis.用于毛细管电泳的近场热透镜检测器仪器参数的优化
Appl Spectrosc. 2005 Dec;59(12):1470-9. doi: 10.1366/000370205775142494.
8
Very low optical absorptions and analyte concentrations in water measured by Optimized Thermal Lens Spectrometry.优化热透镜光谱法测量水中的极低光吸收和分析物浓度。
Talanta. 2011 Aug 15;85(2):850-8. doi: 10.1016/j.talanta.2011.04.015. Epub 2011 May 8.
9
Determination of the Dependence of Thermal Diffusivity with Concentration by Thermal Lens as a Sensitive Experimental Technique.利用热透镜作为一种灵敏的实验技术测定热扩散率与浓度的关系
Int J Thermophys. 2020;41(8):105. doi: 10.1007/s10765-020-02685-w. Epub 2020 May 29.
10
Spectral and Non Radiative Decay Studies of Lead Di Bromide Single Crystals by Mode Matched Thermal Lens Technique.利用模式匹配热透镜技术对二溴化铅单晶进行光谱和非辐射衰变研究。
J Fluoresc. 2016 Jul;26(4):1161-5. doi: 10.1007/s10895-016-1819-y. Epub 2016 May 11.

引用本文的文献

1
Features of High-Precision Photothermal Analysis of Liquid Systems by Dual-Beam Thermal Lens Spectrometry.双光束热透镜光谱法对液体系统进行高精度光热分析的特点。
Nanomaterials (Basel). 2024 Oct 1;14(19):1586. doi: 10.3390/nano14191586.
2
The Thermophysical and Physicochemical Properties of the Aqueous Dispersion of Graphene Oxide Dual-Beam Thermal Lens Spectrometry.氧化石墨烯双光束热透镜光谱法水基分散体的热物理和物理化学性质
Nanomaterials (Basel). 2023 Jul 21;13(14):2126. doi: 10.3390/nano13142126.
3
Thermal Diffusivity of Aqueous Dispersions of Silicon Oxide Nanoparticles by Dual-Beam Thermal Lens Spectrometry.

本文引用的文献

1
Recent Progress and Applications of Thermal Lens Spectrometry and Photothermal Beam Deflection Techniques in Environmental Sensing.热透镜光谱法和光热光束偏转技术在环境传感中的最新进展与应用
Sensors (Basel). 2023 Jan 2;23(1):472. doi: 10.3390/s23010472.
2
A multi-thermal-lens approach to evaluation of multi-pass probe beam configuration in thermal lens spectrometry.多热透镜法评估热透镜光谱法中的多通探针光束配置。
Anal Chim Acta. 2020 Mar 1;1100:182-190. doi: 10.1016/j.aca.2019.12.009. Epub 2019 Dec 5.
3
A review of clinical photoacoustic imaging: Current and future trends.
用双光束热透镜光谱法测定氧化硅纳米颗粒水分散体的热扩散率
Nanomaterials (Basel). 2023 Mar 10;13(6):1006. doi: 10.3390/nano13061006.
4
Composition of the Cytochrome Complex with Cardiolipin by Thermal Lens Spectrometry.用热透镜光谱法研究细胞色素复合物与心磷脂的组成。
Molecules. 2023 Mar 16;28(6):2692. doi: 10.3390/molecules28062692.
临床光声成像综述：现状与未来趋势
Photoacoustics. 2019 Nov 7;16:100144. doi: 10.1016/j.pacs.2019.100144. eCollection 2019 Dec.
4
Review on practical photoacoustic microscopy.实用光声显微镜综述。
Photoacoustics. 2019 Aug 9;15:100141. doi: 10.1016/j.pacs.2019.100141. eCollection 2019 Sep.
5
Hydrophobic drug adsorption loss to syringe filters from a perspective of drug delivery.从药物递送角度看疏水性药物在注射器过滤器上的吸附损失
J Pharmacol Toxicol Methods. 2019 Jan-Feb;95:79-85. doi: 10.1016/j.vascn.2018.12.001. Epub 2018 Dec 5.
6
Near-near-infrared thermal lens spectroscopy to assess overtones and combination bands of sulfentrazone pesticide.近红外热透镜光谱法用于评估甲磺草胺农药的泛音和组合带。
Spectrochim Acta A Mol Biomol Spectrosc. 2018 Jan 5;188:32-36. doi: 10.1016/j.saa.2017.06.043. Epub 2017 Jul 4.
7
High sensitivity thermal lens microscopy: Cr-VI trace detection in water.高灵敏度热透镜显微镜：水中六价铬痕量检测。
Talanta. 2017 Aug 1;170:260-265. doi: 10.1016/j.talanta.2017.04.008. Epub 2017 Apr 3.
8
Application of high-performance liquid chromatography combined with ultra-sensitive thermal lens spectrometric detection for simultaneous biliverdin and bilirubin assessment at trace levels in human serum.高效液相色谱结合超灵敏热透镜光谱检测法在人血清中痕量水平下同时评估胆绿素和胆红素的应用。
Talanta. 2016 Jul 1;154:92-8. doi: 10.1016/j.talanta.2016.03.053. Epub 2016 Mar 16.
9
Fast Screening Techniques for Neurotoxigenic Substances and Other Toxicants and Pollutants Based on Thermal Lensing and Microfluidic Chips.基于热透镜和微流控芯片的神经毒性物质及其他毒物和污染物的快速筛选技术
Anal Sci. 2016;32(1):23-30. doi: 10.2116/analsci.32.23.
10
Investigation into photostability of soybean oils by thermal lens spectroscopy.
Spectrochim Acta A Mol Biomol Spectrosc. 2015 Jun 15;145:125-129. doi: 10.1016/j.saa.2015.02.106. Epub 2015 Mar 3.