有机化合物在亚临界水中的溶解度和分解。

Solubility and Decomposition of Organic Compounds in Subcritical Water.

机构信息

Department of Nanotechnology and Advanced Materials, Mersin University, 33343 Mersin, Turkey.

Department of Chemistry, Arts & Science Faculty, Aksaray University, 68100 Aksaray, Turkey.

出版信息

Molecules. 2023 Jan 19;28(3):1000. doi: 10.3390/molecules28031000.

DOI:10.3390/molecules28031000

PMID:36770670

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9920662/

Abstract

In this article, studies on organic solubility and stability in subcritical water reported during the past 25 years have been reviewed. Data on the solubility and decomposition of organic compounds in subcritical water, a green solvent, are needed in environmental remediation, chemistry, chemical engineering, medicine, polymer, food, agriculture, and many other fields. For solubility studies, the experimental systems used to measure solubility, mathematical equations derived and applied for the modeling of the experimentally determined solubility data, and the correlation between the predicated and experimental data have been summarized and discussed. This paper also reviewed organic decomposition under subcritical water conditions. In general, the solubility of organics is significantly enhanced with increasing water temperature. Likewise, the percentage of organic decomposition also increases with higher temperature.

摘要

本文综述了过去 25 年中关于亚临界水中有机物质溶解度和稳定性的研究。在环境修复、化学、化学工程、医学、聚合物、食品、农业和许多其他领域都需要关于绿色溶剂——亚临界水中有机化合物的溶解度和分解的数据。对于溶解度研究，本文总结和讨论了用于测量溶解度的实验系统、为实验确定的溶解度数据建模而推导和应用的数学方程，以及预测和实验数据之间的相关性。本文还回顾了亚临界水条件下的有机分解。一般来说，随着水温的升高，有机物的溶解度显著提高。同样，较高的温度也会增加有机分解的百分比。