Ochoa Mario, Roldán-Varona Pablo, Algorri José Francisco, López-Higuera José Miguel, Rodríguez-Cobo Luis
Photonics Engineering Group, Universidad de Cantabria, 39005 Santander, Spain.
Instituto de Investigación Sanitaria Valdecilla (IDIVAL), 39011 Santander, Spain.
Lab Chip. 2023 Mar 28;23(7):1752-1757. doi: 10.1039/d3lc00052d.
In fused silica, ultrafast laser assisted etching enables high chemical etching rates (>300 μm h) by setting a light polarisation linear and perpendicular to the beam writing direction. However, for many non-planar surfaces and 3D structures, dynamic polarisation control is difficult or not yet possible to implement. In this contribution, we identify a laser inscription regime in which high etching rates are accomplished independently of the light polarisation. In this regime (<15 pulses per μm), we measure etching rates ∼300 μm h (4 hours in NaOH) including femtosecond-pulse energies corresponding to type II modifications. Few pulse inscriptions show a low degree of anisotropy as compared to higher number of pulses, thus enabling the polarisation insensitivity whose mechanisms are discussed. To demonstrate the capabilities of the processing, we fabricate curved and square-wave microchannels together with a complex 3D geometrical structure (stellated octahedron) containing an inter-plane arrangement with challenging angles (45°), which are difficult to achieve even employing dynamic polarisation control.
在熔融石英中,超快激光辅助蚀刻通过将光偏振设置为与光束写入方向线性且垂直,可实现较高的化学蚀刻速率(>300μm/h)。然而,对于许多非平面表面和三维结构,动态偏振控制难以实现或尚无法实施。在本论文中,我们确定了一种激光刻写模式,在该模式下可实现与光偏振无关的高蚀刻速率。在此模式下(每微米<15个脉冲),我们测量了蚀刻速率约为300μm/h(在NaOH中蚀刻4小时),包括对应于II型改性的飞秒脉冲能量。与较多脉冲数相比,少脉冲刻写显示出较低的各向异性程度,从而实现了偏振不敏感,并对其机制进行了讨论。为了展示该加工能力,我们制作了弯曲和方波微通道以及一个复杂的三维几何结构(星状八面体),该结构包含具有挑战性角度(45°)的面间排列,即使采用动态偏振控制也难以实现。