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氟化银（I）（AgF）的晶体结构重新研究

Crystal structure reinvestigation of silver(I) fluoride, AgF.

作者信息

Lozinšek Matic, Belak Vivod Matic, Dragomir Mirela

机构信息

Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana, Slovenia.

Jožef Stefan International Postgraduate School, Jamova cesta 39, 1000, Ljubljana, Slovenia.

出版信息

IUCrdata. 2023 Jan 24;8(Pt 1):x230018. doi: 10.1107/S2414314623000184. eCollection 2023 Jan.

DOI:10.1107/S2414314623000184
PMID:36794053
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9912324/
Abstract

A crystal structure reinvestigation of AgF based on a low-temperature high-resolution single-crystal X-ray diffraction data is reported. Silver(I) fluoride crystallizes in the rock salt structure type ( ) with a unit-cell parameter of 4.92171 (14) Å at 100 K, resulting in an Ag-F bond length of 2.46085 (7) Å.

摘要

报道了基于低温高分辨率单晶X射线衍射数据对AgF晶体结构的重新研究。氟化银（I）以岩盐结构类型（ ）结晶，在100 K时晶胞参数为4.92171 (14) Å，Ag-F键长为2.46085 (7) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da63/9912324/821955f9de69/x-08-x230018-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da63/9912324/821955f9de69/x-08-x230018-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da63/9912324/821955f9de69/x-08-x230018-fig1.jpg

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Recent developments in the Inorganic Crystal Structure Database: theoretical crystal structure data and related features.无机晶体结构数据库的最新进展：理论晶体结构数据及相关特征
J Appl Crystallogr. 2019 Sep 23;52(Pt 5):918-925. doi: 10.1107/S160057671900997X. eCollection 2019 Oct 1.
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High-Pressure Behavior of Silver Fluorides up to 40 GPa.高达40吉帕斯卡压力下氟化银的高压行为。
Anion-templated silver nanoclusters: precise synthesis and geometric structure.
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Dalton Trans. 2017 Nov 7;46(43):14742-14745. doi: 10.1039/c7dt03178e.
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Structural features of Ag[AuF4] and Ag[AuF6] and the stuctural relationship of Ag[AgF4]2 and Au[AuF4]2 to Ag[AuF4]2.
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