一氧化碳和氢化物形成碳-碳键：金属甲酰中间体的作用。
Carbon-Carbon Bond Formation from Carbon Monoxide and Hydride: The Role of Metal Formyl Intermediates.
机构信息
Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, 82 Wood Lane, Shepherds Bush, London, W12 0BZ, UK.
出版信息
Angew Chem Int Ed Engl. 2023 May 2;62(19):e202219203. doi: 10.1002/anie.202219203. Epub 2023 Mar 2.
Abstract
Current examples of carbon chain production from metal formyl intermediates with homogeneous metal complexes are described in this Minireview. Mechanistic aspects of these reactions as well as the challenges and opportunities in using this understanding to develop new reactions of CO and H are also discussed.
摘要
本文综述了均相金属配合物中金属甲酰中间体生成碳链的最新实例。讨论了这些反应的机理方面，以及利用这一认识开发 CO 和 H 的新反应所面临的挑战和机遇。
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