一种通过将柱[5]芳烃穿套在基于离子对识别的杯[4]吡咯超分子聚合物上构建的聚准轮烷。
A poly-pseudorotaxane constructed by threading pillar[5]arene onto an ion-pair recognition-based calix[4]pyrrole supramolecular polymer.
作者信息
Bektas Necla, Aydogan Abdullah
机构信息
Department of Chemistry, Istanbul Technical University, Maslak 34469, Istanbul, Türkiye.
出版信息
Org Biomol Chem. 2023 Mar 1;21(9):1862-1867. doi: 10.1039/d2ob02268k.
PMID:36799237
Abstract
The ion-pair recognition ability of calix[4]pyrrole was utilized to form a multicomponent monomeric assembly and a linear supramolecular polymer concurrent anion and bis-cation complexation. The inherent dynamic interactions of these assemblies were further used to construct pseudorotaxanes in monomeric and supramolecular polymer forms with pillar[5]arene.
摘要
利用杯[4]吡咯的离子对识别能力，通过同时进行阴离子和双阳离子络合形成多组分单体组装体和线性超分子聚合物。这些组装体固有的动态相互作用进一步用于构建单体形式和超分子聚合物形式的与柱[5]芳烃的准轮烷。
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