Department of Mechanical & Industrial Engineering, Montana State University, 220 Roberts Hall, Bozeman, Montana 59717, United States.
Department of Mechanical Engineering, University of Colorado Boulder, 1111 Engineering Drive, Boulder, Colorado 80309, United States.
ACS Appl Mater Interfaces. 2023 Mar 1;15(8):11084-11091. doi: 10.1021/acsami.2c21925. Epub 2023 Feb 17.
Compliant sutures surrounded by stiff matrices are present in biological armors and carapaces, providing enhanced mechanical performance. Understanding the mechanisms through which these sutured composites achieve outstanding properties is key to developing engineering materials with improved strength and toughness. This article studies the impact of suture geometry and load direction on the performance of suture joints using a two-stage reactive polymer resin that enables facile photopatterning of mechanical heterogeneity within a single polymer network. Compliant sinusoidal sutures with varying geometries are photopatterned into stiff matrices, generating a modulus contrast of 2 orders of magnitude. Empirical relationships are developed connecting suture wavelength and amplitude to composite performance under parallel and perpendicular loading conditions. Results indicate that a greater suture interdigitation broadly improves composite performance when loading is applied perpendicular to suture joints but has deleterious effects when loading is applied parallel to the joint. Investigations into the failure mechanisms under perpendicular loading highlight the interplay between suture geometry and crack growth stability after damage initiation occurs. Our findings could enable a framework for engineering composites and bio-inspired structures in the future.
在生物盔甲和甲壳中,存在被刚性基质包围的柔顺缝线,这为其提供了增强的机械性能。了解这些缝合复合材料实现优异性能的机制是开发具有更高强度和韧性的工程材料的关键。本文使用两阶段反应性聚合物树脂研究了缝线几何形状和负载方向对缝线接头性能的影响,该树脂可在单个聚合物网络内实现机械各向异性的简便光图案化。将具有不同几何形状的柔顺正弦缝线光图案化到刚性基质中,产生了 2 个数量级的模量对比度。建立了经验关系,将缝线波长和振幅与平行和垂直加载条件下的复合材料性能联系起来。结果表明,当负载垂直于缝线接头施加时,更大的缝线交错广泛改善了复合材料的性能,但当负载平行于接头施加时,会产生有害影响。在垂直加载下对失效机制的研究强调了缝线几何形状和损伤起始后裂纹扩展稳定性之间的相互作用。我们的研究结果可以为未来的工程复合材料和仿生结构提供一个框架。