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三维碳整体纳米 TiO 涂层用于微生物燃料电池阳极增强。

Three-Dimensional Carbon Monolith Coated by Nano-TiO for Anode Enhancement in Microbial Fuel Cells.

机构信息

School of Civil Engineering and Architecture, Wuhan University of Technology, Wuhan 430062, China.

出版信息

Int J Environ Res Public Health. 2023 Feb 15;20(4):3437. doi: 10.3390/ijerph20043437.

DOI:10.3390/ijerph20043437
PMID:36834138
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9966231/
Abstract

A three-dimensional (3D) anode is essential for high-performance microbial fuel cells (MFCs). In this study, 3D porous carbon monoliths from a wax gourd (WGCM) were obtained by freeze-drying and carbonization. Nano-TiO was further coated onto the surface of WGCM to obtain a nano-TiO/WGCM anode. The WGCM anode enhanced the maximum power density of MFCs by 167.9% compared with the carbon felt anode, while nano-TiO/WGCM anode additionally increased the value by 45.8% to achieve 1396.2 mW/m. WGCM enhancement was due to the 3D porous structure, the good conductivity and the surface hydrophilicity, which enhanced electroactive biofilm formation and anodic electron transfer. In addition, nano-TiO modification enhanced the enrichment of , an electricigen, by 31.0% on the anode to further improve the power production. The results demonstrated that the nano-TiO/WGCM was an effective anode for power enhancement in MFCs.

摘要

三维(3D)阳极对于高性能微生物燃料电池(MFC)至关重要。在这项研究中,通过冷冻干燥和碳化从冬瓜(WGCM)中获得了 3D 多孔碳单体。进一步在 WGCM 表面涂覆纳米 TiO,得到纳米 TiO/WGCM 阳极。与碳毡阳极相比,WGCM 阳极将 MFC 的最大功率密度提高了 167.9%,而纳米 TiO/WGCM 阳极则将该值进一步提高了 45.8%,达到 1396.2 mW/m。WGCM 的增强归因于 3D 多孔结构、良好的导电性和表面亲水性,这促进了电活性生物膜的形成和阳极电子转移。此外,纳米 TiO 修饰增强了阳极上产电菌的富集,提高了 31.0%,从而进一步提高了产电量。结果表明,纳米 TiO/WGCM 是 MFC 中增强功率的有效阳极。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a81/9966231/770f1adb090c/ijerph-20-03437-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a81/9966231/34ec5793cff3/ijerph-20-03437-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a81/9966231/e478210df467/ijerph-20-03437-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a81/9966231/a127109366a2/ijerph-20-03437-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a81/9966231/770f1adb090c/ijerph-20-03437-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a81/9966231/34ec5793cff3/ijerph-20-03437-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a81/9966231/e478210df467/ijerph-20-03437-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a81/9966231/a127109366a2/ijerph-20-03437-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a81/9966231/770f1adb090c/ijerph-20-03437-g004.jpg

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本文引用的文献

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Modification of carbon felt anodes using double-oxidant HNO/HO for application in microbial fuel cells.使用双氧化剂HNO₃/H₂O₂对碳毡阳极进行改性以应用于微生物燃料电池。
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A dual chamber microbial fuel cell based biosensor for monitoring copper and arsenic in municipal wastewater.基于双室微生物燃料电池的生物传感器用于监测城市废水中的铜和砷。
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Active N dopant states of electrodes regulate extracellular electron transfer of Shewanella oneidensis MR-1 for bioelectricity generation: Experimental and theoretical investigations.电极中活性 N 掺杂态调控 Shewanella oneidensis MR-1 的细胞外电子传递以用于生物电能产生:实验和理论研究。
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