Effect of High-Pressure Torsion and Annealing on the Structure, Phase Composition, and Microhardness of the Ti-18Zr-15Nb (at. %) Alloy.

The Ti-18Zr-15Nb shape memory alloys are a new material for medical implants. The regularities of phase transformations during heating of this alloy in the coarse-grained quenched state and the nanostructured state after high-pressure torsion have been studied. The specimens in quenched state (Q) and HPT state were annealed at 300-550 °C for 0.5, 3, and 12 h. The -phase formation in Ti-18Zr-15Nb alloy occurs by C-shaped kinetics with a pronounced peak near 400-450 °C for Q state and near 350-450 °C for HPT state, and stops or slows down at higher and lower annealing temperatures. The formation of a nanostructured state in the Ti-18Zr-15Nb alloy as a result of HPT suppresses the phase transformation during low-temperature annealing (300-350 °C), but activates the phase transformation. In the Q-state the -phase during annealing at 450-500 °C is formed in the form of plates with a length of tens of microns. The -phase formed during annealing of nanostructured specimens has the appearance of nanosized particle-grains of predominantly equiaxed shape, distributed between the nanograins of -phase. The changes in microhardness during annealing of Q-specimens correlate with changes in phase composition during aging.