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用于高效光催化剂的TiO（锐钛矿、金红石、板钛矿、TiO (B)）的多相多晶型：制备与活性

Heterophase Polymorph of TiO (Anatase, Rutile, Brookite, TiO (B)) for Efficient Photocatalyst: Fabrication and Activity.

作者信息

Eddy Diana Rakhmawaty, Permana Muhamad Diki, Sakti Lintang Kumoro, Sheha Geometry Amal Nur, Hidayat Sahrul, Takei Takahiro, Kumada Nobuhiro, Rahayu Iman

机构信息

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran, Sumedang 45363, West Java, Indonesia.

Integrated Graduate School of Medicine, Engineering, and Agricultural Sciences, University of Yamanashi, Kofu 400-8511, Japan.

出版信息

Nanomaterials (Basel). 2023 Feb 12;13(4):704. doi: 10.3390/nano13040704.

DOI:10.3390/nano13040704
PMID:36839072
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9965282/
Abstract

TiO exists naturally in three crystalline forms: Anatase, rutile, brookite, and TiO (B). These polymorphs exhibit different properties and consequently different photocatalytic performances. This paper aims to clarify the differences between titanium dioxide polymorphs, and the differences in homophase, biphase, and triphase properties in various photocatalytic applications. However, homophase TiO has various disadvantages such as high recombination rates and low adsorption capacity. Meanwhile, TiO heterophase can effectively stimulate electron transfer from one phase to another causing superior photocatalytic performance. Various studies have reported the biphase of polymorph TiO such as anatase/rutile, anatase/brookite, rutile/brookite, and anatase/TiO (B). In addition, this paper also presents the triphase of the TiO polymorph. This review is mainly focused on information regarding the heterophase of the TiO polymorph, fabrication of heterophase synthesis, and its application as a photocatalyst.

摘要

二氧化钛自然存在三种晶体形式

锐钛矿型、金红石型、板钛矿型以及TiO (B)。这些多晶型物表现出不同的性质，因此具有不同的光催化性能。本文旨在阐明二氧化钛多晶型物之间的差异，以及在各种光催化应用中同相、双相和三相性质的差异。然而，同相TiO存在各种缺点，如高复合率和低吸附能力。同时，TiO异相可以有效地刺激电子从一相转移到另一相，从而产生优异的光催化性能。各种研究报道了多晶型TiO的双相，如锐钛矿型/金红石型、锐钛矿型/板钛矿型、金红石型/板钛矿型以及锐钛矿型/TiO (B)。此外，本文还介绍了TiO多晶型的三相。本综述主要关注有关TiO多晶型异相、异相合成制备及其作为光催化剂应用的信息。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/b2330f5a8c54/nanomaterials-13-00704-g014.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/e5ff7f0940e8/nanomaterials-13-00704-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/dc02f0823c58/nanomaterials-13-00704-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/9022c24df4cd/nanomaterials-13-00704-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/4525c42154ee/nanomaterials-13-00704-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/94a9a29b86fe/nanomaterials-13-00704-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/b578ecb4dcf3/nanomaterials-13-00704-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/b2330f5a8c54/nanomaterials-13-00704-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/b7b59ea066f6/nanomaterials-13-00704-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/faa0124debf7/nanomaterials-13-00704-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/47f6c9c71dd0/nanomaterials-13-00704-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/14f68b3955db/nanomaterials-13-00704-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/cc30c8d4dcda/nanomaterials-13-00704-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/2a7b431895db/nanomaterials-13-00704-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/2cb31fea375e/nanomaterials-13-00704-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/e5ff7f0940e8/nanomaterials-13-00704-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/dc02f0823c58/nanomaterials-13-00704-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/9022c24df4cd/nanomaterials-13-00704-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/4525c42154ee/nanomaterials-13-00704-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/94a9a29b86fe/nanomaterials-13-00704-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/b578ecb4dcf3/nanomaterials-13-00704-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dc0c/9965282/b2330f5a8c54/nanomaterials-13-00704-g014.jpg

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