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基于铁氧体和碳纤维的橡胶复合材料的固化、性能及电磁干扰吸收屏蔽

Curing, Properties and EMI Absorption Shielding of Rubber Composites Based on Ferrites and Carbon Fibres.

作者信息

Kruželák Ján, Kvasničáková Andrea, Džuganová Michaela, Hašková Lenka, Dosoudil Rastislav, Hudec Ivan

机构信息

Department of Plastics, Rubber and Fibres, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Radlinského 9, 812 37 Bratislava, Slovakia.

Department of Electromagnetic Theory, Faculty of Electrical Engineering and Information Technology, Slovak University of Technology in Bratislava, Iľkovičova 3, 812 19 Bratislava, Slovakia.

出版信息

Polymers (Basel). 2023 Feb 9;15(4):857. doi: 10.3390/polym15040857.

Abstract

In this work, magnetic soft ferrites, namely manganese-zinc ferrite, nickel-zinc ferrite and combinations of both fillers, were incorporated into acrylonitrile-butadiene rubber to fabricate composite materials. The total content of ferrites was kept constant-300 phr. The second series of composites was fabricated with a similar composition. Moreover, carbon fibres were incorporated into rubber compounds in constant amount-25 phr. The work was focused on investigation of the fillers on absorption shieling performance of the composites, which was investigated within the frequency range 1-6 GHz. Then, the physical-mechanical properties of the composites were evaluated. The achieved results demonstrated that the absorption shielding efficiency of both composite types increased with increasing proportion of nickel-zinc ferrite, which suggests that nickel-zinc ferrite demonstrated better absorption shielding potential. Higher electrical conductivity and higher permittivity of composites filled with carbon fibres and ferrites resulted in their lower absorption shielding performance. Simultaneously, they absorbed electromagnetic radiation at lower frequencies. On the other hand, carbon fibres reinforced the rubber matrix, and subsequent improvement in physical-mechanical properties was recorded.

摘要

在这项工作中,将磁性软铁氧体,即锰锌铁氧体、镍锌铁氧体以及两种填料的组合,加入到丙烯腈 - 丁二烯橡胶中以制备复合材料。铁氧体的总含量保持恒定为300 phr。第二组复合材料以相似的组成制备。此外,将碳纤维以恒定含量25 phr加入到橡胶混合物中。这项工作的重点是研究填料对复合材料吸收屏蔽性能的影响,该性能在1 - 6 GHz频率范围内进行了研究。然后,对复合材料的物理机械性能进行了评估。所获得的结果表明,两种类型复合材料的吸收屏蔽效率均随着镍锌铁氧体比例的增加而提高,这表明镍锌铁氧体具有更好的吸收屏蔽潜力。填充有碳纤维和铁氧体的复合材料具有较高的电导率和介电常数,导致其吸收屏蔽性能较低。同时,它们在较低频率下吸收电磁辐射。另一方面,碳纤维增强了橡胶基体,并记录到物理机械性能随后得到了改善。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7df9/9959415/ad793ad29827/polymers-15-00857-g001.jpg

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