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通过在CuO上负载CoO构建电催化双位点来增强亚硝酸盐电还原为氨的过程。

Enhancing electro-reduction of nitrite to ammonia by loading CoO on CuO to construct elecrocatalytic dual-sites.

作者信息

Zhou Yan, Meng Yunlong, Wang Xingzhao, Luo Jiabing, Xia Hanhan, Li Wenle, Zhang Jun

机构信息

School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, P. R. China.

出版信息

Dalton Trans. 2023 Mar 14;52(11):3260-3264. doi: 10.1039/d2dt03720c.

Abstract

Improving the performance of CuO in electrocatalytic nitrite reduction to ammonia (NIRA) is the priority for designing efficient NIRA electrocatalysts. The electrocatalytic activity of CuO was enhanced by growing CoO nanospheres on it. By comparing CoO@CuO with the mechanically mixed CuO and CoO on a rotating ring-disk electrode, we discovered that the enhancement was attributed to a dual-site catalytic pathway.

摘要

提高CuO在电催化亚硝酸盐还原制氨(NIRA)中的性能是设计高效NIRA电催化剂的首要任务。通过在CuO上生长CoO纳米球,提高了其电催化活性。通过在旋转环盘电极上比较CoO@CuO与机械混合的CuO和CoO,我们发现这种增强归因于双位点催化途径。

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