可见光介导的硫糖与苯胺的施塔德勒-齐格勒芳基化反应

Zhu Mingxiang, Ghouilem Juba, Messaoudi Samir

Université Paris-Saclay, CNRS, BioCIS, 92290 Châtenay-Malabry, France.

ACS Org Inorg Au. 2022 Mar 28;2(4):351-358. doi: 10.1021/acsorginorgau.2c00006. eCollection 2022 Aug 3.

Here, we report a one-pot Stadler-Ziegler reaction toward the synthesis of 1-thioglycosides in good yield from commercially available anilines and (un)protected 1-glycosyl thiols. This simple and mild approach employs the photoredox catalyst Ru(bpy) under visible light.

在此，我们报道了一种一锅法施塔德勒-齐格勒反应，可从市售苯胺和（未）保护的1-糖基硫醇高产率地合成1-硫代糖苷。这种简单温和的方法在可见光下使用光氧化还原催化剂Ru(bpy) 。