Roy Sourav, Chatterjee Indranil
Department of Chemistry, Indian Institute of Technology Ropar, Nangal Road, Rupnagar, Punjab-140001, India.
ACS Org Inorg Au. 2022 Mar 29;2(4):306-311. doi: 10.1021/acsorginorgau.2c00008. eCollection 2022 Aug 3.
A synthetically beneficial visible-light-mediated protocol has been disclosed to achieve C-H amination of readily available feedstocks cyclic and acyclic ethers. A rarely identified -bromosuccinamide-tetrahydrofuran electron donor-acceptor complex served as an initiator to functionalize both α-diazoketones and dialkyl azodicarboxylates. This developed methodology gives an alternative and milder way to construct the C-N bond and can be explored for the formation of C-C bond to perform arylation and allylation reactions.
一种具有综合优势的可见光介导方法已被公开，用于实现易得原料环状和非环状醚的C-H胺化。一种罕见的α-溴代琥珀酰胺-四氢呋喃电子供体-受体络合物用作引发剂，使α-重氮酮和偶氮二甲酸二烷基酯均官能化。这种开发的方法为构建C-N键提供了一种替代且更温和的方式，并且可用于探索形成C-C键以进行芳基化和烯丙基化反应。
