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硼作为前生物对映体富集的假设参与者。

Boron as a Hypothetical Participant in the Prebiological Enantiomeric Enrichment.

机构信息

Centro de Química Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Lisboa, Portugal.

Department of Civil Engineering, Architecture and Georesources, CERENA (Centro de Recursos Naturais e Ambiente), Instituto Superior Técnico, University of Lisbon, Lisbon, Portugal.

出版信息

Astrobiology. 2023 May;23(5):605-615. doi: 10.1089/ast.2022.0077. Epub 2023 Mar 1.

Abstract

Boron, as borate (or boric acid), is known as a mediator of the synthesis of ribose, ribonucleosides, and ribonucleotides (precursors of RNA) under plausible prebiotic conditions. With regard to these phenomena, the potential participation of this chemical element (as a constituent of minerals or hydrogels) for the emergence of prebiological homochirality is considered. This hypothesis is based on characteristics of crystalline surfaces as well as solubility of some minerals of boron in water or specific features of hydrogels with ester bonds from reaction of ribonucleosides and borate.

摘要

硼,以硼酸(或硼酸)的形式,已知是在合理的前生物条件下合成核糖、核糖核苷和核糖核苷酸(RNA 的前体)的介质。就这些现象而言,考虑了这种化学元素(作为矿物质或水凝胶的组成部分)对于前生物手性出现的潜在参与。该假设基于晶体表面的特性以及硼的某些矿物质在水或具有酯键的水凝胶中的溶解度,这些酯键来自核糖核苷和硼酸的反应。

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