Department of Chemistry, The University of Georgia, Athens, Georgia 30602-2556, United States.
J Am Chem Soc. 2023 Mar 15;145(10):5592-5612. doi: 10.1021/jacs.2c13574. Epub 2023 Mar 6.
Carbenes have evolved from transient laboratory curiosities to a robust, diverse, and surprisingly impactful ligand class. A variety of different carbenes have significantly contributed to the development of low-oxidation state main group chemistry. This Perspective focuses upon advances in the chemistry of carbene complexes containing main group element cores in the formal oxidation state of zero, including their diverse synthetic strategies, unusual bonding and structural motifs, and utility in transition metal coordination chemistry and activation of small molecules.
卡宾已经从实验室中的短暂好奇心发展成为一种强大、多样且具有惊人影响力的配体类别。各种不同的卡宾对低价态主族化学的发展做出了重要贡献。本综述聚焦于具有零价主族元素核心的卡宾配合物的化学进展，包括其多样的合成策略、不寻常的成键和结构模式，以及在过渡金属配位化学和小分子活化中的应用。
