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比较流化床和炉排炉焚烧炉底灰中玻璃、金属和矿物质的数量和质量。

Comparing the quantity and quality of glass, metals, and minerals present in waste incineration bottom ashes from a fluidized bed and a grate incinerator.

机构信息

Christian Doppler Laboratory for a Recycling-based Circular Economy, Institute of Chemical, Environmental and Bioscience Engineering (ICEBE), TU Wien, Getreidemarkt 9/166, 1060 Vienna, Austria; Christian Doppler Laboratory for Anthropogenic Resources, Institute for Water Quality and Resource Management, TU Wien, Karlsplatz 13/226, 1040 Vienna, Austria.

Christian Doppler Laboratory for Anthropogenic Resources, Institute for Water Quality and Resource Management, TU Wien, Karlsplatz 13/226, 1040 Vienna, Austria.

出版信息

Waste Manag. 2023 Apr 15;161:142-155. doi: 10.1016/j.wasman.2023.02.021. Epub 2023 Mar 4.

Abstract

Bottom ash is the primary solid residue arising from municipal solid waste incineration. It consists of valuable materials such as minerals, metals and glass. Recovering these materials from bottom ash becomes evident when integrating Waste-to-Energy within the circular economy strategy. To assess the recycling potential from bottom ash, detailed knowledge of its characteristics and composition is required. The study at hand aims to compare the quantity and quality of recyclable materials present in bottom ash from a fluidized bed combustion plant and a grate incinerator, both located in the same city in Austria and receiving mainly municipal solid waste. The investigated properties of the bottom ash are grain-size distribution, contents of recyclable metals, glass, and minerals in different grain size fractions, and the total and leaching contents of substances in minerals. The study results reveal that most recyclables present are of better quality for the bottom ash arising at the fluidized bed combustion plant. Metals are less corroded, glass contains fewer impurities, minerals contain fewer heavy metals, and their leaching behavior is also favorable. Furthermore, recoverable materials, such as metals and glass are more isolated and not incorporated into agglomerates as observed in grate incineration bottom ash. Based on the input to the incinerators more aluminum and significantly more glass can potentially be recovered from bottom ash from fluidized bed combustion. On the downside, fluidized bed combustion produces about five times more fly ash per unit of waste incinerated, which is currently disposed of in landfills.

摘要

底灰是城市固体废物焚烧产生的主要固体残余物。它由有价值的材料组成,如矿物质、金属和玻璃。当废物能源回收策略整合到循环经济中时,从底灰中回收这些材料变得非常重要。为了评估底灰的回收潜力,需要详细了解其特性和组成。本研究旨在比较位于奥地利同一城市的流化床燃烧厂和炉排炉底灰中可回收材料的数量和质量,这两个焚烧厂主要接收城市固体废物。研究的底灰特性包括粒度分布、可回收金属、玻璃和不同粒度级分中的矿物质含量,以及矿物质中物质的总量和浸出含量。研究结果表明,流化床燃烧厂底灰中大多数可回收物的质量更好。金属腐蚀程度较低,玻璃杂质较少,矿物质中重金属含量较低,浸出行为也较有利。此外,可回收材料,如金属和玻璃,在炉排炉底灰中更加隔离,没有与团块结合。基于进入焚烧炉的废物量,流化床燃烧厂底灰中可回收的铝量更多,玻璃量也显著增加。不利的是,流化床燃烧每单位焚烧废物产生的飞灰量约为炉排炉的五倍,目前这些飞灰都被填埋。

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