四配位硼化合物构建方面的最新进展。
Recent advances in the construction of tetracoordinate boron compounds.
作者信息
Li Xue, Zhang Guan, Song Qiuling
机构信息
Institute of Next Generation Matter Transformation, College of Material Sciences Engineering at Huaqiao University, 668 Jimei Blvd, Xiamen, Fujian, 361021, China.
Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry at Fuzhou University, Fuzhou, Fujian, 350108, China.
出版信息
Chem Commun (Camb). 2023 Mar 28;59(26):3812-3820. doi: 10.1039/d2cc06982b.
Tetracoordinate boron compounds are a highly important class of molecules, which are the key intermediates in many organoboron-related chemical transformations and have unique luminescence properties. However, the synthesis of tetracoordinate boron compounds has never been reviewed. In this highlight, we summarize recent progress on the construction of racemic and chiral tetracoordinate borons, and hope to provide ideas for the assembly of them in more efficient ways, especially for the construction of boron-stereogenic compounds.
四配位硼化合物是一类非常重要的分子，它们是许多有机硼相关化学转化中的关键中间体，并且具有独特的发光特性。然而，四配位硼化合物的合成从未被综述过。在本综述中，我们总结了外消旋和手性四配位硼构建方面的最新进展，并希望为以更高效的方式组装它们提供思路，特别是对于硼立体中心化合物的构建。
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