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添加磁性生物炭对污水污泥常温厌氧消化的影响。

Effects of Magnetic Biochar Addition on Mesophilic Anaerobic Digestion of Sewage Sludge.

机构信息

College of Resources and Environment, Yangtze University, Wuhan 430100, China.

State Key Laboratory of Utilization of Woody Oil Resource, Hunan Academy of Forestry, Changsha 410004, China.

出版信息

Int J Environ Res Public Health. 2023 Feb 28;20(5):4278. doi: 10.3390/ijerph20054278.

Abstract

As a low-cost additive to anaerobic digestion (AD), magnetic biochar (MBC) can act as an electron conductor to promote electron transfer to enhance biogas production performance in the AD process of sewage sludge and has thus attracted much attention in research and industrial applications. In the present work, (COS) was used to produce MBC as an additive for mesophilic AD of sewage sludge, in order to explore the effect of MBC on the mesophilic AD process and its enhancement mechanism. Analysis by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), Fourier-transform infrared spectrometry (FTIR), and X-ray diffraction (XRD) further confirmed that biochar was successfully magnetized. The yield of biogas from sewage sludge was enhanced by 14.68-39.24% with the addition of MBC, and the removal efficiency of total solid (TS), volatile solids (VS), and soluble chemical oxygen demand (sCOD) were 28.99-46.13%, 32.22-48.62%, and 84.18-86.71%, respectively. According to the Modified Gompertz Model and Cone Model, the optimum dosage of MBC was 20 mg/g TS. The maximum methane production rate (R) was 15.58% higher than that of the control reactor, while the lag-phase (λ) was 43.78% shorter than the control group. The concentration of soluble Fe and Fe were also detected in this study to analyze the function of MBC for improving biogas production performance from sewage sludge. The biogas production was increased when soluble Fe was reduced to soluble Fe. Overall, the MBC was beneficial to the resource utilization of COS and showed a good prospect for improving mesophilic AD performance.

摘要

作为厌氧消化(AD)的低成本添加剂,磁性生物炭(MBC)可以作为电子导体,促进电子转移,从而提高污水污泥 AD 过程中的沼气产量性能,因此在研究和工业应用中受到了广泛关注。本工作采用连二亚硫酸盐(COS)制备 MBC 作为污水污泥中温 AD 的添加剂,以探索 MBC 对中温 AD 过程的影响及其增强机制。扫描电子显微镜(SEM)、能谱(EDS)、傅里叶变换红外光谱(FTIR)和 X 射线衍射(XRD)分析进一步证实了生物炭成功地被磁化。添加 MBC 可使污水污泥的沼气产量提高 14.68-39.24%,总固体(TS)、挥发性固体(VS)和可溶解性化学需氧量(sCOD)的去除效率分别为 28.99-46.13%、32.22-48.62%和 84.18-86.71%。根据修正的 Gompertz 模型和 Cone 模型,MBC 的最佳投加量为 20mg/gTS。最大甲烷产率(R)比对照反应器高 15.58%,而滞后期(λ)比对照组短 43.78%。本研究还检测了可溶性 Fe 和 Fe 的浓度,以分析 MBC 提高污水污泥产沼气性能的作用。当可溶性 Fe 还原为可溶性 Fe 时,沼气产量增加。总的来说,MBC 有利于 COS 的资源利用,对改善中温 AD 性能具有良好的前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9a87/10001653/1a8632eba0f4/ijerph-20-04278-g001.jpg

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