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一种制备适用于多种基材的无氟耐用超疏水涂层的简单便捷方法。

A Simple and Convenient Method for Preparing Fluorine-Free Durable Superhydrophobic Coatings Suitable for Multiple Substrates.

作者信息

Xu Bin, Zhou Yinping, Gan Shichang, Xu Qinqin, Hou Maohua, Lu Congda, Ni Zhongjin

机构信息

College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China.

College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.

出版信息

Materials (Basel). 2023 Feb 21;16(5):1771. doi: 10.3390/ma16051771.

DOI:10.3390/ma16051771
PMID:36902886
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10003939/
Abstract

Superhydrophobic coatings have attracted a lot of attention due to their excellent self-cleaning and anti-fouling capabilities. However, the preparation processes for several superhydrophobic coatings are intricate and expensive, which restricts their usefulness. In this work, we present a straightforward technique for creating durable superhydrophobic coatings that can be applied to a variety of substrates. The addition of C9 petroleum resin to a styrene-butadiene-styrene (SBS) solution lengthens the SBS backbone and undergoes a cross-linking reaction to form a dense spatial cross-linked structure, improving the storage stability, viscosity, and aging resistance of the SBS. The combined solution functions as a more stable and effective adhesive. Using a two-step spraying technique, the hydrophobic silica (SiO) nanoparticles solution was applied to the surface to create durable nano-superhydrophobic coatings. Additionally, the coatings have excellent mechanical, chemical, and self-cleaning stability. Furthermore, the coatings have wide application prospects in the fields of water-oil separation and corrosion prevention.

摘要

超疏水涂层因其出色的自清洁和防污能力而备受关注。然而,几种超疏水涂层的制备过程复杂且昂贵,这限制了它们的实用性。在这项工作中,我们提出了一种简单的技术来制备耐用的超疏水涂层,该涂层可应用于各种基材。将C9石油树脂添加到苯乙烯-丁二烯-苯乙烯(SBS)溶液中可延长SBS主链并发生交联反应,形成致密的空间交联结构,提高SBS的储存稳定性、粘度和耐老化性。该混合溶液用作更稳定有效的粘合剂。采用两步喷涂技术,将疏水性二氧化硅(SiO)纳米颗粒溶液涂覆在表面上,以制备耐用的纳米超疏水涂层。此外,这些涂层具有优异的机械、化学和自清洁稳定性。此外,这些涂层在油水分离和防腐领域具有广阔的应用前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/4e6ecefc96bd/materials-16-01771-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/df058a814515/materials-16-01771-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/e75107ebc857/materials-16-01771-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/3f0e31dec449/materials-16-01771-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/6702c9800eb7/materials-16-01771-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/929a44a580d0/materials-16-01771-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/98fa0aeaa06d/materials-16-01771-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/f7bcc83ba4bc/materials-16-01771-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/8945a8af3ac5/materials-16-01771-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/bbe930b79c9f/materials-16-01771-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/4e6ecefc96bd/materials-16-01771-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/df058a814515/materials-16-01771-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/e75107ebc857/materials-16-01771-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/3f0e31dec449/materials-16-01771-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/6702c9800eb7/materials-16-01771-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/929a44a580d0/materials-16-01771-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/98fa0aeaa06d/materials-16-01771-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/f7bcc83ba4bc/materials-16-01771-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/8945a8af3ac5/materials-16-01771-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/bbe930b79c9f/materials-16-01771-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ddd9/10003939/4e6ecefc96bd/materials-16-01771-g010.jpg

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本文引用的文献

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Designing Re-Entrant Geometry: Construction of a Superamphiphobic Surface with Large-Sized Particles.设计再入几何形状:用大尺寸颗粒构建超疏水表面。
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Robust Superhydrophobic Cotton Fibers Prepared by Simple Dip-Coating Approach Using Chemical and Plasma-Etching Pretreatments.
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