Zaccardi Federica, Toto Elisa, Marra Fabrizio, Santonicola Maria Gabriella, Laurenzi Susanna
Department of Astronautical Electrical and Energy Engineering, Sapienza University of Rome, Via Salaria 851-881, 00138 Rome, Italy.
Department of Chemical Engineering Materials Environment, Sapienza University of Rome, Via del Castro Laurenziano 7, 00161 Rome, Italy.
Polymers (Basel). 2023 Feb 25;15(5):1163. doi: 10.3390/polym15051163.
In this work, we investigate the processability and the volumetric electrical properties of nanocomposites made of aerospace-grade RTM6, loaded with different carbon nanoparticles. Nanocomposites with graphene nanoplatelets (GNP), single-walled carbon nanotubes (SWCNT) and hybrid GNP/SWCNT in the ratio 2:8 (GNPSWCNT), 5:5 (GNPSWCNT) and 8:2 (GNPSWCNT) were manufactured and analyzed. The hybrid nanofillers are observed to have synergistic properties as epoxy/hybrid mixtures showed better processability than epoxy/SWCNT, while maintaining high values of electrical conductivity. On the other hand, epoxy/SWCNT nanocomposites present the highest electrical conductivities with the formation of a percolating conductive network at lower filler content, but very large viscosity values and filler dispersion issues, which significantly affect the final quality of the samples. Hybrid nanofiller allows us to overcome the manufacturing issues typically associated with the use of SWCNTs. The combination of low viscosity and high electrical conductivity makes the hybrid nanofiller a good candidate for the fabrication of aerospace-grade nanocomposites with multifunctional properties.
在这项工作中,我们研究了由航空航天级RTM6制成的、负载不同碳纳米颗粒的纳米复合材料的加工性能和体积电学性能。制备并分析了含有石墨烯纳米片(GNP)、单壁碳纳米管(SWCNT)以及比例为2:8(GNPSWCNT)、5:5(GNPSWCNT)和8:2(GNPSWCNT)的GNP/SWCNT混合物的纳米复合材料。观察到混合纳米填料具有协同性能,因为环氧/混合混合物显示出比环氧/SWCNT更好的加工性能,同时保持了高电导率值。另一方面,环氧/SWCNT纳米复合材料在较低填料含量下形成渗流导电网络时具有最高的电导率,但具有非常高的粘度值和填料分散问题,这显著影响了样品的最终质量。混合纳米填料使我们能够克服通常与使用SWCNT相关的制造问题。低粘度和高电导率的结合使混合纳米填料成为制造具有多功能性能的航空航天级纳米复合材料的良好候选材料。