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玉米淀粉/纳米原纤纤维素(CS/NFC)和玉米淀粉/纳米原纤木质素(CS/NFLC)薄膜的制备、特性及土壤生物降解分析。

Preparation, characteristics, and soil-biodegradable analysis of corn starch/nanofibrillated cellulose (CS/NFC) and corn starch/nanofibrillated lignocellulose (CS/NFLC) films.

机构信息

Department of Soil Science, Gorgan University of Agricultural Sciences and Natural Resources, Gorgan, Iran.

Department of Paper Science and Engineering, Gorgan University of Agricultural Sciences and Natural Resources, Gorgan, Iran.

出版信息

Carbohydr Polym. 2023 Jun 1;309:120699. doi: 10.1016/j.carbpol.2023.120699. Epub 2023 Feb 15.

Abstract

The objective of this study was to produce high-performance and biodegradable starch nanocomposites through film casting by using corn starch/nanofibrillated cellulose (CS/NFC) and corn starch/nanofibrillated lignocellulose (CS/NFLC). NFC and NFLC were obtained by super grinding process and added to fibrogenic solutions (1, 3, and 5 g/100 g of starch). The addition of NFC and NFLC from 1 to 5 % was verified to be influential in enhancing mechanical properties (tensile, burst, and tear index) and reducing WVTR, air permeability, and essential properties in food packaging materials. But, in comparison to control samples, the addition of NFC and NFLC from 1 to 5 % decreased the opacity, transparency, and tear index of films. In acidic solutions, produced films were more soluble than in alkaline or water solutions. The soil-biodegradability analysis showed that after 30 days of exposure to soil, the control film lost 79.5 % of its weight. The weight loss of all films was >81 % after 40 days. The results of this study may contribute to expanding the industrial applications of both NFC and NFLC by laying a basis for preparing high-performance CS/NFC or CS/NFLC.

摘要

本研究的目的是通过薄膜铸造生产高性能和可生物降解的淀粉纳米复合材料,使用玉米淀粉/纳米原纤化纤维素(CS/NFC)和玉米淀粉/纳米原纤化木质纤维素(CS/NFLC)。NFC 和 NFLC 通过超磨工艺获得,并添加到纤维形成溶液中(1、3 和 5 g/100 g 淀粉)。已验证 NFC 和 NFLC 的添加量从 1%至 5%对增强机械性能(拉伸、破裂和撕裂指数)和降低 WVTR、空气渗透率以及食品包装材料的基本性能有影响。但是,与对照样品相比,NFC 和 NFLC 的添加量从 1%至 5%降低了薄膜的不透明度、透明度和撕裂指数。在酸性溶液中,所制备的薄膜比在碱性或水溶液中更易溶解。土壤生物降解性分析表明,在暴露于土壤 30 天后,对照薄膜失去了 79.5%的重量。所有薄膜在 40 天后的失重率均超过 81%。本研究的结果可能有助于通过为制备高性能 CS/NFC 或 CS/NFLC 奠定基础,从而扩展 NFC 和 NFLC 的工业应用。

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