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原纤化纳米纤维素与由高得率浆所制纸张热压之间的协同作用。

Synergies between Fibrillated Nanocellulose and Hot-Pressing of Papers Obtained from High-Yield Pulp.

作者信息

Negro Carlos, Pettersson Gunilla, Mattsson Amanda, Nyström Staffan, Sanchez-Salvador Jose Luis, Blanco Angeles, Engstrand Per

机构信息

Department of Chemical Engineering and Materials, University Complutense of Madrid, Avda Complutense s/n, 28040 Madrid, Spain.

Department of Engineering, Mathematics and Science Education (IMD), Mid Sweden University, SE-85170 Sundsvall, Sweden.

出版信息

Nanomaterials (Basel). 2023 Jun 25;13(13):1931. doi: 10.3390/nano13131931.

Abstract

To extend the application of cost-effective high-yield pulps in packaging, strength and barrier properties are improved by advanced-strength additives or by hot-pressing. The aim of this study is to assess the synergic effects between the two approaches by using nanocellulose as a bulk additive, and by hot-pressing technology. Due to the synergic effect, dry strength increases by 118% while individual improvements are 31% by nanocellulose and 92% by hot-pressing. This effect is higher for mechanical fibrillated cellulose. After hot-pressing, all papers retain more than 22% of their dry strength. Hot-pressing greatly increases the paper's ability to withstand compressive forces applied in short periods of time by 84%, with a further 30% increase due to the synergic effect of the fibrillated nanocellulose. Hot-pressing and the fibrillated cellulose greatly decrease air permeability (80% and 68%, respectively) for refining pretreated samples, due to the increased fiber flexibility, which increase up to 90% using the combined effect. The tear index increases with the addition of nanocellulose, but this effect is lost after hot-pressing. In general, fibrillation degree has a small effect which means that low- cost nanocellulose could be used in hot-pressed papers, providing products with a good strength and barrier capacity.

摘要

为了扩大高性价比高产纸浆在包装领域的应用,可通过添加高强度添加剂或热压来提高纸张的强度和阻隔性能。本研究的目的是通过使用纳米纤维素作为填充添加剂并结合热压技术,评估这两种方法之间的协同效应。由于协同效应,干强度提高了118%,而单独使用纳米纤维素时强度提高31%,单独热压时强度提高92%。这种效应在机械原纤化纤维素中更为显著。热压后,所有纸张保留了超过22%的干强度。热压极大地提高了纸张在短时间内承受压缩力的能力,提高了84%,由于原纤化纳米纤维素的协同效应,这一能力进一步提高了30%。对于经过磨浆预处理的样品,热压和原纤化纤维素极大地降低了透气率(分别降低80%和68%),这是由于纤维柔韧性增加,综合作用下透气率降低高达90%。撕裂指数随着纳米纤维素的添加而增加,但热压后这种效果消失。总体而言,原纤化程度影响较小,这意味着低成本的纳米纤维素可用于热压纸张,为产品提供良好的强度和阻隔性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee7/10343211/61caa566462f/nanomaterials-13-01931-g001.jpg

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