在金属有机框架内直接生成用于半加氢催化剂的聚吡咯包覆钯纳米颗粒。
Direct generation of polypyrrole-coated palladium nanoparticles inside a metal-organic framework for a semihydrogenation catalyst.
作者信息
Takashima Yohei, Tetsusashi Seiko, Tanaka Shintaro, Tsuruoka Takaaki, Akamatsu Kensuke
机构信息
Department of Nanobiochemistry, Frontiers of Innovative Research in Science and Technolgoy (FIRST), Konan University 7-1-20 Minatojimaminamimachi, Chuo-ku Kobe 650-0047 Japan
出版信息
RSC Adv. 2023 Mar 8;13(11):7464-7467. doi: 10.1039/d2ra08190c. eCollection 2023 Mar 1.
Herein, the direct synthesis of polypyrrole (PPy)-coated palladium nanoparticles (PdNPs) inside a metal-organic framework (MIL-101) was successfully demonstrated. Owing to the PPy coating of PdNPs, the resulting composites exhibited higher semihydrogenation capability (selectivity: up to 96%) than the analog composite without PPy coating.
在此，我们成功地证明了在金属有机框架（MIL-101）内部直接合成聚吡咯（PPy）包覆的钯纳米颗粒（PdNPs）。由于PdNPs的PPy包覆，所得复合材料表现出比没有PPy包覆的类似复合材料更高的半氢化能力（选择性：高达96%）。
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