Kahr Bart
Department of Chemistry and Molecular Design Institute, New York University, 29 Washington Place, New York City, NY 10003, USA.
Acta Crystallogr E Crystallogr Commun. 2023 Feb 7;79(Pt 3):124-128. doi: 10.1107/S2056989023000786. eCollection 2023 Feb 1.
There are about 100 chemical elements, and 200 space groups, rounding to the nearest hundreds. The elements, by virtue of the iconic periodic table, which hangs in schoolrooms worldwide, are part of our common culture. Few on the outside of solid-state science and discrete mathematics know of the remarkable enumeration of the space groups and how they organize solids, the chemical elements included, that can be conformed to translationally periodic lattices in three dimensions. Perhaps the comparative inaccessibility of space groups to non-specialists can be attributed to the absence of a single chart that captures and organizes the space groups in a glance, as does the periodic table for the chemical elements? Here is designed a periodic-like table of the space groups. The symmorphic space groups are organized as the coordinates of two non-linear, non-orthogonal axes that capture the point group symmetry and the order of the group, the multiplicity of general positions. The related non-symmorphic groups are treated as 'isotopes' of the symmorphic groups and are enumerated with a subscript. The intent is to inspire better designs and to bring the crystallographic space groups to the attention of a wider audience.
大约有100种化学元素,以及200种空间群,四舍五入到最接近的百位数。借助悬挂在世界各地教室中的标志性元素周期表,这些元素已成为我们共同文化的一部分。固态科学和离散数学领域之外的人很少了解空间群的非凡枚举以及它们如何组织固体,包括化学元素,这些固体可以符合三维平移周期晶格。也许空间群对于非专业人士来说比较难以接触,这可以归因于缺乏一张能像化学元素周期表那样一眼就能捕捉和组织空间群的图表?这里设计了一个类似周期表的空间群表。对称空间群被组织成两个非线性、非正交轴的坐标,这两个轴捕捉点群对称性和群的阶数,即一般位置的多重性。相关的非对称群被视为对称群的“同位素”,并用下标进行枚举。目的是激发更好的设计,并让更广泛的受众关注晶体学空间群。