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Syntheses and crystal structure of a (2,6-diiso-propyldi-naphtho-[2,1-:1',2'-][1,3]dithiepin-4-yl)(phen-yl)methanol atropisomer.

作者信息

Beare Neil, Painter Gavin F, McAdam C John

机构信息

BDG Synthesis, PO Box 38627, Wellington Mail Centre 5045, Wellington, New Zealand.

Ferrier Research Institute, Victoria University of Wellington, PO Box 33436, Lower Hutt 5046, New Zealand.

出版信息

Acta Crystallogr E Crystallogr Commun. 2023 Feb 28;79(Pt 3):241-245. doi: 10.1107/S2056989023001706. eCollection 2023 Feb 1.

DOI:10.1107/S2056989023001706
PMID:36909995
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9993907/
Abstract

The racemic title compound, CHOS, comprises an atropisomeric binaphthyl di-thio-acetal substituted at the methyl-ene carbon atom with a chiral benzyl alcohol. The two naphthalene ring systems are additionally substituted at the 3,3'-position with isopropyl groups. The overall stereochemistry is defined as and . The hydroxyl group forms an intra-molecular O-H⋯S hydrogen bond to one of the sulfur atoms. The crystal structure contains weak C-H⋯π inter-actions that link the mol-ecules into extended arrays.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/d3ac25a19e54/e-79-00241-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/5976914d2843/e-79-00241-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/e870b92075a3/e-79-00241-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/81f8672b8ef0/e-79-00241-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/0f1b5f4832be/e-79-00241-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/0a0987e300a7/e-79-00241-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/d3ac25a19e54/e-79-00241-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/5976914d2843/e-79-00241-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/e870b92075a3/e-79-00241-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/81f8672b8ef0/e-79-00241-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/0f1b5f4832be/e-79-00241-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/0a0987e300a7/e-79-00241-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c765/9993907/d3ac25a19e54/e-79-00241-fig6.jpg

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本文引用的文献

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